A new three-dimensional vanadium selenite, (VO)(2)(SeO3)(3), with isolated and edge-shared VO6 octahedra
Single crystals of (VO)2(SeO3)3 have been prepared from SeO2 and V2O5. The crystal structure has been determined by single-crystal X-ray diffraction. Crystal data: (VO)2(SeO3)3, Mr = 514.75; monoclinic, space group P21a (No. 14); cell parameters a = 9.151(1) Å, b = 6.353(1) Å, c = 14.992(1)Å, β = 93...
| Váldodahkkit: | , |
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| Materiálatiipa: | Journal article |
| Giella: | English |
| Almmustuhtton: |
1997
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| _version_ | 1826269634726199296 |
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| author | Halasyamani, P O'Hare, D |
| author_facet | Halasyamani, P O'Hare, D |
| author_sort | Halasyamani, P |
| collection | OXFORD |
| description | Single crystals of (VO)2(SeO3)3 have been prepared from SeO2 and V2O5. The crystal structure has been determined by single-crystal X-ray diffraction. Crystal data: (VO)2(SeO3)3, Mr = 514.75; monoclinic, space group P21a (No. 14); cell parameters a = 9.151(1) Å, b = 6.353(1) Å, c = 14.992(1)Å, β = 93.538(5)°, and Z = 4. The structure consists of VO6 octahedra and SeO3 groups. The vanadium octahedra either are edge-sharing and form [V2O6.66]3.33- groups or are corner-linked through an [SeO3/2]+ cation. The structure may be rationalized in terms of connecting layers of {2[SeO2/2O1/3]4/3+[VO1/1O 4/2O1/3]5/3-}+ cations and {[SeO3/2]+[VO1/1O5/2]2-}- anions. © 1997 American Chemical Society. |
| first_indexed | 2024-03-06T21:28:07Z |
| format | Journal article |
| id | oxford-uuid:43c874bf-fd1a-4a86-9a0b-5f3d1421cf6f |
| institution | University of Oxford |
| language | English |
| last_indexed | 2024-03-06T21:28:07Z |
| publishDate | 1997 |
| record_format | dspace |
| spelling | oxford-uuid:43c874bf-fd1a-4a86-9a0b-5f3d1421cf6f2022-03-26T14:57:34ZA new three-dimensional vanadium selenite, (VO)(2)(SeO3)(3), with isolated and edge-shared VO6 octahedraJournal articlehttp://purl.org/coar/resource_type/c_dcae04bcuuid:43c874bf-fd1a-4a86-9a0b-5f3d1421cf6fEnglishSymplectic Elements at Oxford1997Halasyamani, PO'Hare, DSingle crystals of (VO)2(SeO3)3 have been prepared from SeO2 and V2O5. The crystal structure has been determined by single-crystal X-ray diffraction. Crystal data: (VO)2(SeO3)3, Mr = 514.75; monoclinic, space group P21a (No. 14); cell parameters a = 9.151(1) Å, b = 6.353(1) Å, c = 14.992(1)Å, β = 93.538(5)°, and Z = 4. The structure consists of VO6 octahedra and SeO3 groups. The vanadium octahedra either are edge-sharing and form [V2O6.66]3.33- groups or are corner-linked through an [SeO3/2]+ cation. The structure may be rationalized in terms of connecting layers of {2[SeO2/2O1/3]4/3+[VO1/1O 4/2O1/3]5/3-}+ cations and {[SeO3/2]+[VO1/1O5/2]2-}- anions. © 1997 American Chemical Society. |
| spellingShingle | Halasyamani, P O'Hare, D A new three-dimensional vanadium selenite, (VO)(2)(SeO3)(3), with isolated and edge-shared VO6 octahedra |
| title | A new three-dimensional vanadium selenite, (VO)(2)(SeO3)(3), with isolated and edge-shared VO6 octahedra |
| title_full | A new three-dimensional vanadium selenite, (VO)(2)(SeO3)(3), with isolated and edge-shared VO6 octahedra |
| title_fullStr | A new three-dimensional vanadium selenite, (VO)(2)(SeO3)(3), with isolated and edge-shared VO6 octahedra |
| title_full_unstemmed | A new three-dimensional vanadium selenite, (VO)(2)(SeO3)(3), with isolated and edge-shared VO6 octahedra |
| title_short | A new three-dimensional vanadium selenite, (VO)(2)(SeO3)(3), with isolated and edge-shared VO6 octahedra |
| title_sort | new three dimensional vanadium selenite vo 2 seo3 3 with isolated and edge shared vo6 octahedra |
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