Marcus theory for outer-sphere heterogeneous electron transfer: Predicting electron-transfer rates for quinones
Steady-state voltammetry is used to measure the heterogeneous electron-transfer rates for the reduction of quinones to determine the dependence of k0 on molecular size, according to Marcus theory. This dependence is then used to predict the electron-transfer rate constants of related quinones, and t...
| প্রধান লেখক: | , , , , |
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| বিন্যাস: | Journal article |
| ভাষা: | English |
| প্রকাশিত: |
2004
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| সংক্ষিপ্ত: | Steady-state voltammetry is used to measure the heterogeneous electron-transfer rates for the reduction of quinones to determine the dependence of k0 on molecular size, according to Marcus theory. This dependence is then used to predict the electron-transfer rate constants of related quinones, and the predictions are compared to experimental measurements. |
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