Marcus theory for outer-sphere heterogeneous electron transfer: Predicting electron-transfer rates for quinones
Steady-state voltammetry is used to measure the heterogeneous electron-transfer rates for the reduction of quinones to determine the dependence of k0 on molecular size, according to Marcus theory. This dependence is then used to predict the electron-transfer rate constants of related quinones, and t...
| Hlavní autoři: | , , , , |
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| Médium: | Journal article |
| Jazyk: | English |
| Vydáno: |
2004
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| _version_ | 1826269667420798976 |
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| author | Rees, N Clegg, A Klymenko, O Coles, B Compton, R |
| author_facet | Rees, N Clegg, A Klymenko, O Coles, B Compton, R |
| author_sort | Rees, N |
| collection | OXFORD |
| description | Steady-state voltammetry is used to measure the heterogeneous electron-transfer rates for the reduction of quinones to determine the dependence of k0 on molecular size, according to Marcus theory. This dependence is then used to predict the electron-transfer rate constants of related quinones, and the predictions are compared to experimental measurements. |
| first_indexed | 2024-03-06T21:28:41Z |
| format | Journal article |
| id | oxford-uuid:43f207ca-06f4-4937-963e-6bda7b51b72c |
| institution | University of Oxford |
| language | English |
| last_indexed | 2024-03-06T21:28:41Z |
| publishDate | 2004 |
| record_format | dspace |
| spelling | oxford-uuid:43f207ca-06f4-4937-963e-6bda7b51b72c2022-03-26T14:58:36ZMarcus theory for outer-sphere heterogeneous electron transfer: Predicting electron-transfer rates for quinonesJournal articlehttp://purl.org/coar/resource_type/c_dcae04bcuuid:43f207ca-06f4-4937-963e-6bda7b51b72cEnglishSymplectic Elements at Oxford2004Rees, NClegg, AKlymenko, OColes, BCompton, RSteady-state voltammetry is used to measure the heterogeneous electron-transfer rates for the reduction of quinones to determine the dependence of k0 on molecular size, according to Marcus theory. This dependence is then used to predict the electron-transfer rate constants of related quinones, and the predictions are compared to experimental measurements. |
| spellingShingle | Rees, N Clegg, A Klymenko, O Coles, B Compton, R Marcus theory for outer-sphere heterogeneous electron transfer: Predicting electron-transfer rates for quinones |
| title | Marcus theory for outer-sphere heterogeneous electron transfer: Predicting electron-transfer rates for quinones |
| title_full | Marcus theory for outer-sphere heterogeneous electron transfer: Predicting electron-transfer rates for quinones |
| title_fullStr | Marcus theory for outer-sphere heterogeneous electron transfer: Predicting electron-transfer rates for quinones |
| title_full_unstemmed | Marcus theory for outer-sphere heterogeneous electron transfer: Predicting electron-transfer rates for quinones |
| title_short | Marcus theory for outer-sphere heterogeneous electron transfer: Predicting electron-transfer rates for quinones |
| title_sort | marcus theory for outer sphere heterogeneous electron transfer predicting electron transfer rates for quinones |
| work_keys_str_mv | AT reesn marcustheoryforoutersphereheterogeneouselectrontransferpredictingelectrontransferratesforquinones AT clegga marcustheoryforoutersphereheterogeneouselectrontransferpredictingelectrontransferratesforquinones AT klymenkoo marcustheoryforoutersphereheterogeneouselectrontransferpredictingelectrontransferratesforquinones AT colesb marcustheoryforoutersphereheterogeneouselectrontransferpredictingelectrontransferratesforquinones AT comptonr marcustheoryforoutersphereheterogeneouselectrontransferpredictingelectrontransferratesforquinones |