Marcus theory for outer-sphere heterogeneous electron transfer: Predicting electron-transfer rates for quinones

Steady-state voltammetry is used to measure the heterogeneous electron-transfer rates for the reduction of quinones to determine the dependence of k0 on molecular size, according to Marcus theory. This dependence is then used to predict the electron-transfer rate constants of related quinones, and t...

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Príomhchruthaitheoirí: Rees, N, Clegg, A, Klymenko, O, Coles, B, Compton, R
Formáid: Journal article
Teanga:English
Foilsithe / Cruthaithe: 2004