Marcus theory for outer-sphere heterogeneous electron transfer: Predicting electron-transfer rates for quinones

Marcus theory for outer-sphere heterogeneous electron transfer: Predicting electron-transfer rates for quinones

Steady-state voltammetry is used to measure the heterogeneous electron-transfer rates for the reduction of quinones to determine the dependence of k0 on molecular size, according to Marcus theory. This dependence is then used to predict the electron-transfer rate constants of related quinones, and t...

Bibliografiset tiedot
Päätekijät:	Rees, N, Clegg, A, Klymenko, O, Coles, B, Compton, R
Aineistotyyppi:	Journal article
Kieli:	English
Julkaistu:	2004

Samankaltaisia teoksia

Experimental validation of Marcus theory for outer-sphere heterogeneous electron-transfer reactions: the oxidation of substituted 1,4-phenylenediamines.
Tekijä: Clegg, A, et al.
Julkaistu: (2004)

Marcus theory of outer-sphere heterogeneous electron transfer reactions: High precision steady-state measurements of the standard electrochemical rate constant for ferrocene derivatives in alkyl cyanide solvents
Tekijä: Clegg, A, et al.
Julkaistu: (2005)

Marcus theory of outer-sphere heterogeneous electron transfer reactions: dependence of the standard electrochemical rate constant on the hydrodynamic radius from high precision measurements of the oxidation of anthracene and its derivatives in nonaqueous solvents using the high-speed channel electrode.
Tekijä: Clegg, A, et al.
Julkaistu: (2004)

Optimal rates for electron transfer in Marcus theory
Tekijä: Mourokh, Lev, et al.
Julkaistu: (2014)

Marcus-Hush-Chidsey theory of electron transfer applied to voltammetry: A review
Tekijä: Henstridge, M, et al.
Julkaistu: (2012)

Marcus-Hush-Chidsey theory of electron transfer applied to voltammetry: A review
Tekijä: Henstridge, M, et al.
Julkaistu: (2012)

Reassessment of the Four-Point Approach to the Electron-Transfer Marcus–Hush Theory
Tekijä: Omar López-Estrada, et al.
Julkaistu: (2018-02-01)

Electron Transfer at Molecule–Metal Interfaces under Floquet Engineering: Rate Constant and Floquet Marcus Theory
Tekijä: Yu Wang, et al.
Julkaistu: (2023-12-01)

Molecular insights into electron transfer processes via variable temperature cyclic voltammetry. Application of the asymmetric Marcus-Hush model
Tekijä: Suwatchara, D, et al.
Julkaistu: (2012)

Photochemical electron transfer between methylene blue and quinones
Tekijä: Misni, M., et al.
Julkaistu: (1994)

Marcus-Hush-Chidsey theory of electron transfer to and from species bound at a non-uniform electrode surface: Theory and experiment
Tekijä: Henstridge, M, et al.
Julkaistu: (2011)

Electrocatalysis via intrinsic surface quinones mediating electron transfer to and from carbon electrodes
Tekijä: Li, D, et al.
Julkaistu: (2020)

Syntrophic Growth via Quinone-Mediated Interspecies Electron Transfer
Tekijä: Jessica A Smith, et al.
Julkaistu: (2015-02-01)

Asymmetric Marcus-Hush model of electron transfer kinetics: Application to the voltammetry of surface-bound redox systems
Tekijä: Henstridge, M, et al.
Julkaistu: (2012)

Behavior of the heterogeneous electron-transfer rate constants of arenes and substituted anthracenes in room-temperature ionic liquids
Tekijä: Belding, SR, et al.
Julkaistu: (2008)

Marcus Theory and Tunneling Method for the Electron Transfer Rate Analysis in Quantum Dot Sensitized Solar Cells in the Presence of Blocking Layer
Tekijä: Mohammad Javad Fahimi, et al.
Julkaistu: (2023-09-01)

Metal Ion-/Proton-Coupled Electron Transfer (MPCET) on ortho-Quinone
Tekijä: Divyaratan Kumar, et al.
Julkaistu: (2024-09-01)

Lactiplantibacillus plantarum uses ecologically relevant, exogenous quinones for extracellular electron transfer
Tekijä: Eric T. Stevens, et al.
Julkaistu: (2023-12-01)

The use of differential pulse voltammetries to discriminate between the Butler-Volmer and the simple Marcus-Hush models for heterogeneous electron transfer: The electro-reduction of europium (III) in aqueous solution
Tekijä: Wang, Y, et al.
Julkaistu: (2012)

The use of differential pulse voltammetries to discriminate between the Butler-Volmer and the simple Marcus-Hush models for heterogeneous electron transfer: The electro-reduction of europium (III) in aqueous solution
Tekijä: Wang, Y, et al.
Julkaistu: (2012)

Genomic Analyses of the Quinol Oxidases and/or Quinone Reductases Involved in Bacterial Extracellular Electron Transfer
Tekijä: Yuhong Zhong, et al.
Julkaistu: (2018-12-01)

Variable temperature study of electro-reduction of 3-nitrophenolate via cyclic and square wave voltammetry: Molecular insights into electron transfer processes based on the asymmetric Marcus-Hush model
Tekijä: Laborda, E, et al.
Julkaistu: (2013)

Variable temperature study of electro-reduction of 3-nitrophenolate via cyclic and square wave voltammetry: Molecular insights Into electron transfer processes based on the asymmetric Marcus-Hush model
Tekijä: Laborda, E, et al.
Julkaistu: (2013)

Electron transfer kinetics at single nanoparticles
Tekijä: Kahk, J, et al.
Julkaistu: (2012)

Electron transfer kinetics at single nanoparticles
Tekijä: Kahk, J, et al.
Julkaistu: (2012)

Access to enhanced differences in Marcus–Hush and Butler–Volmer electron transfer theories by systematic analysis of higher order AC harmonics
Tekijä: Gillow, K, et al.
Julkaistu: (2012)

Voltammetry at graphite electrodes: The oxidation of hexacyanoferrate (II) (ferrocyanide) does not exhibit pure outer-sphere electron transfer kinetics and is sensitive to pre-exposure of the electrode to organic solvents
Tekijä: Xiong, L, et al.
Julkaistu: (2011)

VOLTAMMETRY IN THE PRESENCE OF ULTRASOUND - CAN ULTRASOUND MODIFY HETEROGENEOUS ELECTRON-TRANSFER KINETICS
Tekijä: Marken, F, et al.
Julkaistu: (1995)

Heterogeneous Catalysis of Multiple-Electron-Transfer Reactions at Nanoparticle-Modified Electrodes
Tekijä: Laborda, E, et al.
Julkaistu: (2014)

Liposoluble quinone promotes the reduction of hydrophobic mineral and extracellular electron transfer of Shewanella oneidensis MR-1
Tekijä: Xiaohan Lin, et al.
Julkaistu: (2021-05-01)

Asymmetric Marcus-Hush theory for voltammetry.
Tekijä: Laborda, E, et al.
Julkaistu: (2013)

Mediated Electron Transfer at Redox Active Monolayers. Part 3: Bimolecular Outer-Sphere, First Order Koutecky-Levich and Adduct Formation Mechanisms
Tekijä: Michael E.G. Lyons
Julkaistu: (2002-12-01)

The high speed channel electrode applied to heterogeneous kinetics: the oxidation of 1,4-phenylenediamines and related species in acetonitrile
Tekijä: Rees, N, et al.
Julkaistu: (2002)

In situ EPR studies of electron transfer across a polarised liquid/liquid interface
Tekijä: Dryfe, R, et al.
Julkaistu: (1997)

Nitrogen-Doped Graphene: The Influence of Doping Level on the Charge-Transfer Resistance and Apparent Heterogeneous Electron Transfer Rate
Tekijä: Maria Coros, et al.
Julkaistu: (2020-03-01)

Asymmetric Marcus theory: Application to electrode kinetics
Tekijä: Laborda, E, et al.
Julkaistu: (2012)

Tuning the reduction potential of quinones by controlling the effects of hydrogen bonding, protonation and proton-coupled electron transfer reactions
Tekijä: Shi, Raymond Rong Sheng, et al.
Julkaistu: (2021)

SONOVOLTAMMETRY - HETEROGENEOUS ELECTRON-TRANSFER PROCESSES WITH COUPLED ULTRASONICALLY INDUCED CHEMICAL-REACTION - THE SONO-EC REACTION
Tekijä: Compton, R, et al.
Julkaistu: (1995)

Hydrodynamics and mass transport in wall-tube and microjet electrodes: An experimental evaluation of current theory
Tekijä: Rees, N, et al.
Julkaistu: (2003)

Comparative evaluation of the symmetric and asymmetric Marcus-Hush formalisms of electrode kinetics - The one-electron oxidation of tetraphenylethylene in dichloromethane on platinum microdisk electrodes
Tekijä: Suwatchara, D, et al.
Julkaistu: (2012)