Chelation-controlled intermolecular alkene and alkyne hydroacylation: the utility of beta-thioacetal aldehydes.

Chelation-controlled intermolecular alkene and alkyne hydroacylation: the utility of beta-thioacetal aldehydes.

[reaction: see text]. Beta-thioacetal-substituted aldehydes, which are conveniently prepared from the corresponding ynals, can be combined with a range of alkynes or electron-poor alkenes to deliver intermolecular hydroacylation adducts. The reactions employ [Rh(dppe)]ClO4 as a catalyst and are prop...

Cur síos iomlán

Sonraí bibleagrafaíochta
Príomhchruthaitheoirí:	Willis, M, Randell-Sly, H, Woodward, R, Currie, G
Formáid:	Journal article
Teanga:	English
Foilsithe / Cruthaithe:	2005

Míreanna comhchosúla

Rhodium-catalyzed intermolecular chelation controlled alkene and alkyne hydroacylation: synthetic scope of beta-S-substituted aldehyde substrates.
de réir: Willis, M, et al.
Foilsithe / Cruthaithe: (2006)

Intermolecular alkene and alkyne hydroacylation with beta-S-substituted aldehydes: mechanistic insight into the role of a hemilabile P-O-P ligand.
de réir: Moxham, G, et al.
Foilsithe / Cruthaithe: (2008)

A second-generation catalyst for intermolecular hydroacylation of alkenes and alkynes using beta-S-substituted aldehydes: the role of a hemilabile P-O-P ligand.
de réir: Moxham, G, et al.
Foilsithe / Cruthaithe: (2006)

Traceless chelation-controlled rhodium-catalyzed intermolecular alkene and alkyne hydroacylation.
de réir: Hooper, J, et al.
Foilsithe / Cruthaithe: (2013)

Chelation-controlled intermolecular hydroacylation: direct addition of alkyl aldehydes to functionalized alkenes.
de réir: Willis, M, et al.
Foilsithe / Cruthaithe: (2004)

Catalytic enantioselective intermolecular hydroacylation: rhodium-catalyzed combination of beta-S-aldehydes and 1,3-disubstituted allenes.
de réir: Osborne, J, et al.
Foilsithe / Cruthaithe: (2008)

Hydroacylation of Alkenes, Alkynes, and Allenes
de réir: Willis, M
Foilsithe / Cruthaithe: (2014)

Exploiting carbonyl groups to control intermolecular rhodium-catalyzed alkene and alkyne hydroacylation
de réir: Coxon, TJ, et al.
Foilsithe / Cruthaithe: (2017)

Intermolecular rhodium catalyzed hydroacylation of allenes: the regioselective synthesis of beta,gamma-unsaturated ketones
de réir: Randell-Sly, H, et al.
Foilsithe / Cruthaithe: (2009)

O-substituted alkyl aldehydes for rhodium-catalyzed intermolecular alkyne hydroacylation: the utility of methylthiomethyl ethers.
de réir: Parsons, SR, et al.
Foilsithe / Cruthaithe: (2011)

Transition metal catalyzed alkene and alkyne hydroacylation.
de réir: Willis, M
Foilsithe / Cruthaithe: (2010)

Controlling Selectivity in Intermolecular Alkene or Aldehyde Hydroacylation Reactions Catalyzed by {Rh(L-2)}(+) Fragments
de réir: Pawley, R, et al.
Foilsithe / Cruthaithe: (2010)

Exploring small bite-angle PNP and PCP ligands for the rhodium-catalysed intermolecular hydroacylation of b-s-substituted aldehydes with alkenes and alkynes
de réir: Pernik, I
Foilsithe / Cruthaithe: (2014)

Rhodium(I) catalysis for intermolecular alkyne hydroacylation and desymmetrisation
de réir: Moseley, D
Foilsithe / Cruthaithe: (2022)

α-amino aldehydes as readily available chiral aldehydes for Rh-catalyzed alkyne hydroacylation
de réir: Hooper, JF, et al.
Foilsithe / Cruthaithe: (2016)

Azine N-oxides as effective controlling groups for Rh-catalysed intermolecular alkyne hydroacylation
de réir: Moseley, DF, et al.
Foilsithe / Cruthaithe: (2021)

Replacing dichloroethane as a solvent for rhodium-catalysed intermolecular alkyne hydroacylation reactions: the utility of propylene carbonate
de réir: Lenden, P, et al.
Foilsithe / Cruthaithe: (2011)

α‐Amidoaldehydes as substrates in rhodium‐catalyzed intermolecular alkyne hydroacylation: The synthesis of α‐Amidoketones
de réir: Pal, R, et al.
Foilsithe / Cruthaithe: (2020)

a-Amidoaldehydes as substrates in rhodium-catalyzed intermolecular alkyne hydroacylation: The synthesis of a-amidoketones
de réir: Pal, R, et al.
Foilsithe / Cruthaithe: (2020)

Intermolecular Alkyne Hydroacylation. Mechanistic Insight from the Isolation of the Vinyl Intermediate That Precedes Reductive Elimination
de réir: Pawley, R, et al.
Foilsithe / Cruthaithe: (2012)

Rhodium (I) catalyzed intermolecular hydroacylation.
de réir: Sapmaz, S, et al.
Foilsithe / Cruthaithe: (2001)

Rhodium-catalysed intermolecular alkyne hydroacylation: the enantioselective synthesis of α- and β-substituted ketones by kinetic resolution.
de réir: González-Rodríguez, C, et al.
Foilsithe / Cruthaithe: (2010)

Exploring Small Bite-Angle Ligands for the Rhodium-Catalyzed Intermolecular Hydroacylation of beta-S-Substituted Aldehydes with 1-Octene and 1-Octyne
de réir: Pernik, I, et al.
Foilsithe / Cruthaithe: (2012)

An alkyne hydroacylation route to highly substituted furans.
de réir: Lenden, P, et al.
Foilsithe / Cruthaithe: (2011)

Rhodium-catalysed linear-selective alkyne hydroacylation.
de réir: Poingdestre, S, et al.
Foilsithe / Cruthaithe: (2012)

Rhodium-catalyzed enantioselective intermolecular hydroacylation reactions
de réir: Gonzalez-Rodriguez, C, et al.
Foilsithe / Cruthaithe: (2011)

Difunctionalization of Alkenes and Alkynes via Intermolecular Radical and Nucleophilic Additions
de réir: Hongjun Yao, et al.
Foilsithe / Cruthaithe: (2020-12-01)

An enamine controlling group for rhodium-catalyzed intermolecular hydroacylation
de réir: Straker, R, et al.
Foilsithe / Cruthaithe: (2018)

Synthesis of α,β-unsaturated ketones through nickel-catalysed aldehyde-free hydroacylation of alkynes
de réir: Joon Ho Rhlee, et al.
Foilsithe / Cruthaithe: (2022-02-01)

Diversely substituted quinolines via rhodium-catalyzed alkyne hydroacylation
de réir: Willis, M, et al.
Foilsithe / Cruthaithe: (2016)

Cobalt-catalyzed intermolecular hydroacylation of olefins through chelation-assisted imidoyl C-H activation
de réir: Yang, Junfeng, et al.
Foilsithe / Cruthaithe: (2015)

Mechanistic studies of rhodium-catalysed intermolecular hydroacylation
de réir: Barwick-Silk, J
Foilsithe / Cruthaithe: (2018)

Well‐defined and robust rhodium catalysts for the hydroacylation of terminal and internal alkenes
de réir: Prades, A, et al.
Foilsithe / Cruthaithe: (2015)

Intermolecular hydroacylation of acrylate esters: a new route to 1,4-dicarbonyls
de réir: Willis, M, et al.
Foilsithe / Cruthaithe: (2001)

Controlling selectivity in the rhodium-catalysed intermolecular hydroacylation reaction
de réir: Pawley, R
Foilsithe / Cruthaithe: (2012)

Origins of Regioselectivity and Alkene-Directing Effects in Nickel- Catalyzed Reductive Couplings of Alkynes and Aldehydes
de réir: Jamison, Timothy F., et al.
Foilsithe / Cruthaithe: (2012)

Rhodium-catalyzed branched-selective alkyne hydroacylation: a ligand-controlled regioselectivity switch.
de réir: González-Rodríguez, C, et al.
Foilsithe / Cruthaithe: (2011)

2-Aminobenzaldehydes as versatile substrates for rhodium-catalyzed alkyne hydroacylation: application to dihydroquinolone synthesis.
de réir: Castaing, M, et al.
Foilsithe / Cruthaithe: (2013)

Rh(DPEPhos)-catalyzed alkyne hydroacylation using β-carbonyl-substituted aldehydes: mechanistic insight leads to low catalyst loadings that enables selective catalysis on gram-scale
de réir: Barwick-Silk, J, et al.
Foilsithe / Cruthaithe: (2018)

Tandem catalytic processes involving Rhodium-catalysed intermolecular hydroacylation
de réir: Lenden, P
Foilsithe / Cruthaithe: (2011)