Chelation-controlled intermolecular alkene and alkyne hydroacylation: the utility of beta-thioacetal aldehydes.
[reaction: see text]. Beta-thioacetal-substituted aldehydes, which are conveniently prepared from the corresponding ynals, can be combined with a range of alkynes or electron-poor alkenes to deliver intermolecular hydroacylation adducts. The reactions employ [Rh(dppe)]ClO4 as a catalyst and are prop...
Հիմնական հեղինակներ: | Willis, M, Randell-Sly, H, Woodward, R, Currie, G |
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Ձևաչափ: | Journal article |
Լեզու: | English |
Հրապարակվել է: |
2005
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Նմանատիպ նյութեր
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Rhodium-catalyzed intermolecular chelation controlled alkene and alkyne hydroacylation: synthetic scope of beta-S-substituted aldehyde substrates.
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Intermolecular alkene and alkyne hydroacylation with beta-S-substituted aldehydes: mechanistic insight into the role of a hemilabile P-O-P ligand.
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Հրապարակվել է: (2008) -
A second-generation catalyst for intermolecular hydroacylation of alkenes and alkynes using beta-S-substituted aldehydes: the role of a hemilabile P-O-P ligand.
: Moxham, G, և այլն
Հրապարակվել է: (2006) -
Traceless chelation-controlled rhodium-catalyzed intermolecular alkene and alkyne hydroacylation.
: Hooper, J, և այլն
Հրապարակվել է: (2013) -
Chelation-controlled intermolecular hydroacylation: direct addition of alkyl aldehydes to functionalized alkenes.
: Willis, M, և այլն
Հրապարակվել է: (2004)