Study of the intercalation of lithium salt in gibbsite using time-resolved in situ X-ray diffraction
Time-resolved in situ X-ray diffraction measurements have been used to measure the rate of intercalation of lithium salts (LiX; X = Cl, Br, NO3, OH, and SO4) into Gibbsite (γ-Al(OH)3) giving the layered double hydroxides [LiAl2(OH)6]X·nH2O (X = Cl, Br, NO3, and OH) and [LiAl2(OH)6]2SO4·nH 2O. The te...
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| Format: | Journal article |
| Language: | English |
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1999
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| _version_ | 1797065502933123072 |
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| author | Fogg, A O'Hare, D |
| author_facet | Fogg, A O'Hare, D |
| author_sort | Fogg, A |
| collection | OXFORD |
| description | Time-resolved in situ X-ray diffraction measurements have been used to measure the rate of intercalation of lithium salts (LiX; X = Cl, Br, NO3, OH, and SO4) into Gibbsite (γ-Al(OH)3) giving the layered double hydroxides [LiAl2(OH)6]X·nH2O (X = Cl, Br, NO3, and OH) and [LiAl2(OH)6]2SO4·nH 2O. The temperature dependence of the rate of intercalation of LiCl yields an activation energy of 27 kJ mol-1. The reaction was also found to be half-order with respect to the initial concentration of LiCl. The rate of intercalation is sensitive to the nature of the anions with the half-lives of the reactions varying from 450 to 4800 s going from Li2SO4 to LiNO3. © 1999 American Chemical Society. |
| first_indexed | 2024-03-06T21:29:31Z |
| format | Journal article |
| id | oxford-uuid:4432e032-6187-4b5e-bdfc-b73844319428 |
| institution | University of Oxford |
| language | English |
| last_indexed | 2024-03-06T21:29:31Z |
| publishDate | 1999 |
| record_format | dspace |
| spelling | oxford-uuid:4432e032-6187-4b5e-bdfc-b738443194282022-03-26T15:00:09ZStudy of the intercalation of lithium salt in gibbsite using time-resolved in situ X-ray diffractionJournal articlehttp://purl.org/coar/resource_type/c_dcae04bcuuid:4432e032-6187-4b5e-bdfc-b73844319428EnglishSymplectic Elements at Oxford1999Fogg, AO'Hare, DTime-resolved in situ X-ray diffraction measurements have been used to measure the rate of intercalation of lithium salts (LiX; X = Cl, Br, NO3, OH, and SO4) into Gibbsite (γ-Al(OH)3) giving the layered double hydroxides [LiAl2(OH)6]X·nH2O (X = Cl, Br, NO3, and OH) and [LiAl2(OH)6]2SO4·nH 2O. The temperature dependence of the rate of intercalation of LiCl yields an activation energy of 27 kJ mol-1. The reaction was also found to be half-order with respect to the initial concentration of LiCl. The rate of intercalation is sensitive to the nature of the anions with the half-lives of the reactions varying from 450 to 4800 s going from Li2SO4 to LiNO3. © 1999 American Chemical Society. |
| spellingShingle | Fogg, A O'Hare, D Study of the intercalation of lithium salt in gibbsite using time-resolved in situ X-ray diffraction |
| title | Study of the intercalation of lithium salt in gibbsite using time-resolved in situ X-ray diffraction |
| title_full | Study of the intercalation of lithium salt in gibbsite using time-resolved in situ X-ray diffraction |
| title_fullStr | Study of the intercalation of lithium salt in gibbsite using time-resolved in situ X-ray diffraction |
| title_full_unstemmed | Study of the intercalation of lithium salt in gibbsite using time-resolved in situ X-ray diffraction |
| title_short | Study of the intercalation of lithium salt in gibbsite using time-resolved in situ X-ray diffraction |
| title_sort | study of the intercalation of lithium salt in gibbsite using time resolved in situ x ray diffraction |
| work_keys_str_mv | AT fogga studyoftheintercalationoflithiumsaltingibbsiteusingtimeresolvedinsituxraydiffraction AT ohared studyoftheintercalationoflithiumsaltingibbsiteusingtimeresolvedinsituxraydiffraction |