An approach to insulated molecular wires: synthesis of water-soluble conjugated rotaxanes

Hydrophobic self-assembly has been used to direct the synthesis of conjugated [2] and [3]rotaxanes (20 and 21) in aqueous solution, by Glaser coupling a water-soluble alkyne 3 in the presence of a cyclophane 6. No rotaxanes were formed when cyclodextrins were used instead of the cyclophane. NMR and...

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Main Authors: Anderson, S, Aplin, RT, Claridge, T, Goodson, T, Maciel, A, Rumbles, G, Ryan, J, Anderson, H
格式: Journal article
语言:English
出版: 1998