An approach to insulated molecular wires: synthesis of water-soluble conjugated rotaxanes
Hydrophobic self-assembly has been used to direct the synthesis of conjugated [2] and [3]rotaxanes (20 and 21) in aqueous solution, by Glaser coupling a water-soluble alkyne 3 in the presence of a cyclophane 6. No rotaxanes were formed when cyclodextrins were used instead of the cyclophane. NMR and...
| Hlavní autoři: | , , , , , , , |
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| Médium: | Journal article |
| Jazyk: | English |
| Vydáno: |
1998
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