An approach to insulated molecular wires: synthesis of water-soluble conjugated rotaxanes
Hydrophobic self-assembly has been used to direct the synthesis of conjugated [2] and [3]rotaxanes (20 and 21) in aqueous solution, by Glaser coupling a water-soluble alkyne 3 in the presence of a cyclophane 6. No rotaxanes were formed when cyclodextrins were used instead of the cyclophane. NMR and...
| Main Authors: | , , , , , , , |
|---|---|
| פורמט: | Journal article |
| שפה: | English |
| יצא לאור: |
1998
|