X-ray emission and photoelectron spectra, and the location of fluorine atoms in strontium and calcium copper oxyfluorides

X-ray emission and photoelectron spectra of Sr2CuO2F2+δ, Sr1.4Ba0.6CuO2F2+δ, CaSrCuO2F2+δ, and Ca2CuO2F2+δ cuprates are presented. It is found that the XPS F 1s binding energies of Sr2CuO2F2+δ and Ca2CuO2F2+δ are different (ΔE ∼ 1.3 eV) and those of Sr1.4Ba0.6CuO2F2+δ and CaSrCuO2F2+δ have intermedi...

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Bibliographic Details
Main Authors: Kurmaev, E, Elokhina, L, Fedorenko, V, Bartkowski, S, Neumann, M, Greaves, C, Edwards, P, Slater, P, Francesconi, MG
Format: Journal article
Language:English
Published: 1996