Amperometric determination of sulfide at a pre-oxidised nickel electrode in acidic media.
The electrochemical response of a pre-oxidised nickel electrode to increasing additions of sulfide has been examined and shown to produce a stripping-like voltammetric wave. A mechanism is described based on the formation of nickel sulfide at the electrode surface from a non-electroactive nickel oxi...
| Main Authors: | , , , , |
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| פורמט: | Journal article |
| שפה: | English |
| יצא לאור: |
2003
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| _version_ | 1826270198320070656 |
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| author | Giovanelli, D Lawrence, N Jiang, L Jones, T Compton, R |
| author_facet | Giovanelli, D Lawrence, N Jiang, L Jones, T Compton, R |
| author_sort | Giovanelli, D |
| collection | OXFORD |
| description | The electrochemical response of a pre-oxidised nickel electrode to increasing additions of sulfide has been examined and shown to produce a stripping-like voltammetric wave. A mechanism is described based on the formation of nickel sulfide at the electrode surface from a non-electroactive nickel oxide layer. The analytical utility of the approach has been examined and a linear range from 1 to 140 microM and a limit of detection of 0.8 microM is achievable, depending on the accumulation time. |
| first_indexed | 2024-03-06T21:37:05Z |
| format | Journal article |
| id | oxford-uuid:46a0f635-a8d9-4f5e-b8c6-7c8d764fdfe7 |
| institution | University of Oxford |
| language | English |
| last_indexed | 2024-03-06T21:37:05Z |
| publishDate | 2003 |
| record_format | dspace |
| spelling | oxford-uuid:46a0f635-a8d9-4f5e-b8c6-7c8d764fdfe72022-03-26T15:14:54ZAmperometric determination of sulfide at a pre-oxidised nickel electrode in acidic media.Journal articlehttp://purl.org/coar/resource_type/c_dcae04bcuuid:46a0f635-a8d9-4f5e-b8c6-7c8d764fdfe7EnglishSymplectic Elements at Oxford2003Giovanelli, DLawrence, NJiang, LJones, TCompton, RThe electrochemical response of a pre-oxidised nickel electrode to increasing additions of sulfide has been examined and shown to produce a stripping-like voltammetric wave. A mechanism is described based on the formation of nickel sulfide at the electrode surface from a non-electroactive nickel oxide layer. The analytical utility of the approach has been examined and a linear range from 1 to 140 microM and a limit of detection of 0.8 microM is achievable, depending on the accumulation time. |
| spellingShingle | Giovanelli, D Lawrence, N Jiang, L Jones, T Compton, R Amperometric determination of sulfide at a pre-oxidised nickel electrode in acidic media. |
| title | Amperometric determination of sulfide at a pre-oxidised nickel electrode in acidic media. |
| title_full | Amperometric determination of sulfide at a pre-oxidised nickel electrode in acidic media. |
| title_fullStr | Amperometric determination of sulfide at a pre-oxidised nickel electrode in acidic media. |
| title_full_unstemmed | Amperometric determination of sulfide at a pre-oxidised nickel electrode in acidic media. |
| title_short | Amperometric determination of sulfide at a pre-oxidised nickel electrode in acidic media. |
| title_sort | amperometric determination of sulfide at a pre oxidised nickel electrode in acidic media |
| work_keys_str_mv | AT giovanellid amperometricdeterminationofsulfideatapreoxidisednickelelectrodeinacidicmedia AT lawrencen amperometricdeterminationofsulfideatapreoxidisednickelelectrodeinacidicmedia AT jiangl amperometricdeterminationofsulfideatapreoxidisednickelelectrodeinacidicmedia AT jonest amperometricdeterminationofsulfideatapreoxidisednickelelectrodeinacidicmedia AT comptonr amperometricdeterminationofsulfideatapreoxidisednickelelectrodeinacidicmedia |