Direct observation of the conical intersection in cis-trans photoisomerization of rhodopsin

Direct observation of the conical intersection in cis-trans photoisomerization of rhodopsin

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High-time-resolution broadband pump-probe spectroscopy of rhodopsin reveals loss of reactant and appearance of photoproduct features within ≈100fs, which are signatures of a wavepacket moving through a conical intersection. Experiments are supported by molecular dynamics simulations. © OSA / UP 2010...

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Hlavní autoři: Polli, D, Altoè, P, Weingart, O, Kukura, P, Spillane, K, Manzoni, C, Brida, D, Tomasello, G, Orlandi, G, Mathies, R, Garavelli, M, Cerullo, G
Médium: Journal article
Jazyk:English
Vydáno: 2010

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