Rolie-Poly fluid flowing through constrictions: Two distinct instabilities

Elastic instabilities of entangled polymer melts are common in industrial processes but the physics responsible is not well understood. We present a numerical linear stability study of a molecular-based constitutive model which grants us physical insight into the underlying mechanics involved. Two c...

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Main Authors: Reis, T, Wilson, H
Format: Journal article
Published: 2012
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author Reis, T
Wilson, H
author_facet Reis, T
Wilson, H
author_sort Reis, T
collection OXFORD
description Elastic instabilities of entangled polymer melts are common in industrial processes but the physics responsible is not well understood. We present a numerical linear stability study of a molecular-based constitutive model which grants us physical insight into the underlying mechanics involved. Two constriction flows are considered - one shear dominated, the other extension dominated - and two distinct instabilities are found. The influence of the molecular structure and the behaviour of the polymer dynamics are investigated and in both cases chain relaxation and orientation play a crucial role. Additionally, convective-constraint release is also shown to be critical, but with a contrasting effect in the two flows: when the molecular weight is high, slow release is found to be stabilising in the extension dominated constriction but destabilising in the shear dominated flow. This suggests a molecular-based physical interpretation of the underlying mechanisms responsible for flow instabilities.
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spelling oxford-uuid:474e25cc-5ea0-435c-95c9-8692cd0a7a742022-03-26T15:19:24ZRolie-Poly fluid flowing through constrictions: Two distinct instabilitiesJournal articlehttp://purl.org/coar/resource_type/c_dcae04bcuuid:474e25cc-5ea0-435c-95c9-8692cd0a7a74Mathematical Institute - ePrints2012Reis, TWilson, HElastic instabilities of entangled polymer melts are common in industrial processes but the physics responsible is not well understood. We present a numerical linear stability study of a molecular-based constitutive model which grants us physical insight into the underlying mechanics involved. Two constriction flows are considered - one shear dominated, the other extension dominated - and two distinct instabilities are found. The influence of the molecular structure and the behaviour of the polymer dynamics are investigated and in both cases chain relaxation and orientation play a crucial role. Additionally, convective-constraint release is also shown to be critical, but with a contrasting effect in the two flows: when the molecular weight is high, slow release is found to be stabilising in the extension dominated constriction but destabilising in the shear dominated flow. This suggests a molecular-based physical interpretation of the underlying mechanisms responsible for flow instabilities.
spellingShingle Reis, T
Wilson, H
Rolie-Poly fluid flowing through constrictions: Two distinct instabilities
title Rolie-Poly fluid flowing through constrictions: Two distinct instabilities
title_full Rolie-Poly fluid flowing through constrictions: Two distinct instabilities
title_fullStr Rolie-Poly fluid flowing through constrictions: Two distinct instabilities
title_full_unstemmed Rolie-Poly fluid flowing through constrictions: Two distinct instabilities
title_short Rolie-Poly fluid flowing through constrictions: Two distinct instabilities
title_sort rolie poly fluid flowing through constrictions two distinct instabilities
work_keys_str_mv AT reist roliepolyfluidflowingthroughconstrictionstwodistinctinstabilities
AT wilsonh roliepolyfluidflowingthroughconstrictionstwodistinctinstabilities