Development of dirhodium(II)-catalyzed generation and enantioselective 1,3-dipolar cycloaddition of carbonyl ylides.
Catalytic, enantioselective, tandem carbonyl ylide formation/cycloaddition of 2-diazo-3,6-diketoester 2 with the use of dirhodium tetrakiscarboxylate and tetrakisbinaphtholphosphate catalysts to give the cycloadducts 3 in good yields and up to 90% ee is described.
| Main Authors: | , , , , |
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| 格式: | Journal article |
| 语言: | English |
| 出版: |
2001
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| _version_ | 1826270377935896576 |
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| author | Hodgson, D Stupple, P Pierard, F Labande, A Johnstone, C |
| author_facet | Hodgson, D Stupple, P Pierard, F Labande, A Johnstone, C |
| author_sort | Hodgson, D |
| collection | OXFORD |
| description | Catalytic, enantioselective, tandem carbonyl ylide formation/cycloaddition of 2-diazo-3,6-diketoester 2 with the use of dirhodium tetrakiscarboxylate and tetrakisbinaphtholphosphate catalysts to give the cycloadducts 3 in good yields and up to 90% ee is described. |
| first_indexed | 2024-03-06T21:39:53Z |
| format | Journal article |
| id | oxford-uuid:478ca7d7-7117-45b5-8a0e-25d1f6dda0d5 |
| institution | University of Oxford |
| language | English |
| last_indexed | 2024-03-06T21:39:53Z |
| publishDate | 2001 |
| record_format | dspace |
| spelling | oxford-uuid:478ca7d7-7117-45b5-8a0e-25d1f6dda0d52022-03-26T15:20:43ZDevelopment of dirhodium(II)-catalyzed generation and enantioselective 1,3-dipolar cycloaddition of carbonyl ylides.Journal articlehttp://purl.org/coar/resource_type/c_dcae04bcuuid:478ca7d7-7117-45b5-8a0e-25d1f6dda0d5EnglishSymplectic Elements at Oxford2001Hodgson, DStupple, PPierard, FLabande, AJohnstone, CCatalytic, enantioselective, tandem carbonyl ylide formation/cycloaddition of 2-diazo-3,6-diketoester 2 with the use of dirhodium tetrakiscarboxylate and tetrakisbinaphtholphosphate catalysts to give the cycloadducts 3 in good yields and up to 90% ee is described. |
| spellingShingle | Hodgson, D Stupple, P Pierard, F Labande, A Johnstone, C Development of dirhodium(II)-catalyzed generation and enantioselective 1,3-dipolar cycloaddition of carbonyl ylides. |
| title | Development of dirhodium(II)-catalyzed generation and enantioselective 1,3-dipolar cycloaddition of carbonyl ylides. |
| title_full | Development of dirhodium(II)-catalyzed generation and enantioselective 1,3-dipolar cycloaddition of carbonyl ylides. |
| title_fullStr | Development of dirhodium(II)-catalyzed generation and enantioselective 1,3-dipolar cycloaddition of carbonyl ylides. |
| title_full_unstemmed | Development of dirhodium(II)-catalyzed generation and enantioselective 1,3-dipolar cycloaddition of carbonyl ylides. |
| title_short | Development of dirhodium(II)-catalyzed generation and enantioselective 1,3-dipolar cycloaddition of carbonyl ylides. |
| title_sort | development of dirhodium ii catalyzed generation and enantioselective 1 3 dipolar cycloaddition of carbonyl ylides |
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