The first fully fluorinated organically templated materials: Synthesis, structures, and physical properties of [H3N(CH2)(3)NH3]U2F10 center dot 2H(2)O, [H3N(CH2)(4)NH3]U2F10 center dot 3H(2)O, [H3N(CH2)(6)NH3]U2F10 center dot 2H(2)O, and [HN(CH2CH2NH3)(3)]U5F24
A series of new layered uranium(IV) fluorides have been prepared under hydrothermal conditions from UO2, HF, and H3PO4 by using H2N(CH2)nNH2 (n = 3, 4, or 6), and N(CH2-CH2NH2)3 as structure-directing agents. [H3N(CH2)3NH3]U2F 10·2H2O (UFO-1), [H3N(CH2)4-NH3]U2F 10·3H2O (UFO-2), [H3N(CH2)6NH3]U2F 10...
| Main Authors: | , , |
|---|---|
| Format: | Journal article |
| Language: | English |
| Published: |
1998
|