Enhanced pi conjugation around a porphyrin[6] nanoring.
(Figure Presented) Strong cycle: The cyclic hexamer-template complex 3 obtained through template-directed trimerization of a porphyrin dimer 2, using a hexapyridyl template 1, is extremely stable (Kf=7×10 38m-1), but the free macrocycle 4 can be liberated using amine ligands. Spectroscopic data and...
| Main Authors: | , , , , , |
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| Format: | Journal article |
| Language: | English |
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2008
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| _version_ | 1826270548522434560 |
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| author | Hoffmann, M Kärnbratt, J Chang, M Herz, L Albinsson, B Anderson, H |
| author_facet | Hoffmann, M Kärnbratt, J Chang, M Herz, L Albinsson, B Anderson, H |
| author_sort | Hoffmann, M |
| collection | OXFORD |
| description | (Figure Presented) Strong cycle: The cyclic hexamer-template complex 3 obtained through template-directed trimerization of a porphyrin dimer 2, using a hexapyridyl template 1, is extremely stable (Kf=7×10 38m-1), but the free macrocycle 4 can be liberated using amine ligands. Spectroscopic data and DFT calculations show that the cyclic hexamer is more conjugated than its linear analogue. © 2008 Wiley-VCH Verlag GmbH and Co. KGaA. |
| first_indexed | 2024-03-06T21:42:33Z |
| format | Journal article |
| id | oxford-uuid:486e3596-0291-4b70-86ac-c56d0bebab79 |
| institution | University of Oxford |
| language | English |
| last_indexed | 2024-03-06T21:42:33Z |
| publishDate | 2008 |
| record_format | dspace |
| spelling | oxford-uuid:486e3596-0291-4b70-86ac-c56d0bebab792022-03-26T15:25:47ZEnhanced pi conjugation around a porphyrin[6] nanoring.Journal articlehttp://purl.org/coar/resource_type/c_dcae04bcuuid:486e3596-0291-4b70-86ac-c56d0bebab79EnglishSymplectic Elements at Oxford2008Hoffmann, MKärnbratt, JChang, MHerz, LAlbinsson, BAnderson, H(Figure Presented) Strong cycle: The cyclic hexamer-template complex 3 obtained through template-directed trimerization of a porphyrin dimer 2, using a hexapyridyl template 1, is extremely stable (Kf=7×10 38m-1), but the free macrocycle 4 can be liberated using amine ligands. Spectroscopic data and DFT calculations show that the cyclic hexamer is more conjugated than its linear analogue. © 2008 Wiley-VCH Verlag GmbH and Co. KGaA. |
| spellingShingle | Hoffmann, M Kärnbratt, J Chang, M Herz, L Albinsson, B Anderson, H Enhanced pi conjugation around a porphyrin[6] nanoring. |
| title | Enhanced pi conjugation around a porphyrin[6] nanoring. |
| title_full | Enhanced pi conjugation around a porphyrin[6] nanoring. |
| title_fullStr | Enhanced pi conjugation around a porphyrin[6] nanoring. |
| title_full_unstemmed | Enhanced pi conjugation around a porphyrin[6] nanoring. |
| title_short | Enhanced pi conjugation around a porphyrin[6] nanoring. |
| title_sort | enhanced pi conjugation around a porphyrin 6 nanoring |
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