Size dependent oxygen buffering capacity of ceria nanocrystals
The structural, chemical and electronic changes of ceria as a function of decreasing particle size have been studied: at sizes below 5 nm the total amount of reducible oxygen dramatically increases due to superoxide formation on the ceria surface, a result indicative of a size dependent oxygen buffe...
Main Authors: | , , , , , , |
---|---|
Format: | Journal article |
Language: | English |
Published: |
2010
|
_version_ | 1797066542622441472 |
---|---|
author | Xu, J Harmer, J Li, G Chapman, T Collier, P Longworth, S Tsang, S |
author_facet | Xu, J Harmer, J Li, G Chapman, T Collier, P Longworth, S Tsang, S |
author_sort | Xu, J |
collection | OXFORD |
description | The structural, chemical and electronic changes of ceria as a function of decreasing particle size have been studied: at sizes below 5 nm the total amount of reducible oxygen dramatically increases due to superoxide formation on the ceria surface, a result indicative of a size dependent oxygen buffering capacity. © The Royal Society of Chemistry 2010. |
first_indexed | 2024-03-06T21:43:33Z |
format | Journal article |
id | oxford-uuid:48c6869f-f5d5-468e-8c7b-ea2ec765d151 |
institution | University of Oxford |
language | English |
last_indexed | 2024-03-06T21:43:33Z |
publishDate | 2010 |
record_format | dspace |
spelling | oxford-uuid:48c6869f-f5d5-468e-8c7b-ea2ec765d1512022-03-26T15:27:41ZSize dependent oxygen buffering capacity of ceria nanocrystalsJournal articlehttp://purl.org/coar/resource_type/c_dcae04bcuuid:48c6869f-f5d5-468e-8c7b-ea2ec765d151EnglishSymplectic Elements at Oxford2010Xu, JHarmer, JLi, GChapman, TCollier, PLongworth, STsang, SThe structural, chemical and electronic changes of ceria as a function of decreasing particle size have been studied: at sizes below 5 nm the total amount of reducible oxygen dramatically increases due to superoxide formation on the ceria surface, a result indicative of a size dependent oxygen buffering capacity. © The Royal Society of Chemistry 2010. |
spellingShingle | Xu, J Harmer, J Li, G Chapman, T Collier, P Longworth, S Tsang, S Size dependent oxygen buffering capacity of ceria nanocrystals |
title | Size dependent oxygen buffering capacity of ceria nanocrystals |
title_full | Size dependent oxygen buffering capacity of ceria nanocrystals |
title_fullStr | Size dependent oxygen buffering capacity of ceria nanocrystals |
title_full_unstemmed | Size dependent oxygen buffering capacity of ceria nanocrystals |
title_short | Size dependent oxygen buffering capacity of ceria nanocrystals |
title_sort | size dependent oxygen buffering capacity of ceria nanocrystals |
work_keys_str_mv | AT xuj sizedependentoxygenbufferingcapacityofceriananocrystals AT harmerj sizedependentoxygenbufferingcapacityofceriananocrystals AT lig sizedependentoxygenbufferingcapacityofceriananocrystals AT chapmant sizedependentoxygenbufferingcapacityofceriananocrystals AT collierp sizedependentoxygenbufferingcapacityofceriananocrystals AT longworths sizedependentoxygenbufferingcapacityofceriananocrystals AT tsangs sizedependentoxygenbufferingcapacityofceriananocrystals |