Voltammetry of porous layers: Staircase vs analog voltammetry
The use of staircase ramps for cyclic voltammetry rather than true linear analog ramps can lead to significant misinterpretation of the signals recorded for the measurement of diffusional redox species with either reversible or irreversible electrode kinetics measured at electrodes modified with por...
| Main Authors: | , , |
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| Format: | Journal article |
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Elsevier
2016
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| _version_ | 1797066652895936512 |
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| author | Ban, Z Kätelhön, F Compton, R |
| author_facet | Ban, Z Kätelhön, F Compton, R |
| author_sort | Ban, Z |
| collection | OXFORD |
| description | The use of staircase ramps for cyclic voltammetry rather than true linear analog ramps can lead to significant misinterpretation of the signals recorded for the measurement of diffusional redox species with either reversible or irreversible electrode kinetics measured at electrodes modified with porous layers. Most notably a large perturbation of the expected peak current is apparent which can preclude the extraction of meaningful data, for example in respect of surface coverages or in the identification of electro-catalysis. |
| first_indexed | 2024-03-06T21:45:05Z |
| format | Journal article |
| id | oxford-uuid:494c274b-7825-43a1-ae14-eb7d7cc78743 |
| institution | University of Oxford |
| last_indexed | 2024-03-06T21:45:05Z |
| publishDate | 2016 |
| publisher | Elsevier |
| record_format | dspace |
| spelling | oxford-uuid:494c274b-7825-43a1-ae14-eb7d7cc787432022-03-26T15:30:41ZVoltammetry of porous layers: Staircase vs analog voltammetryJournal articlehttp://purl.org/coar/resource_type/c_dcae04bcuuid:494c274b-7825-43a1-ae14-eb7d7cc78743Symplectic Elements at OxfordElsevier2016Ban, ZKätelhön, FCompton, RThe use of staircase ramps for cyclic voltammetry rather than true linear analog ramps can lead to significant misinterpretation of the signals recorded for the measurement of diffusional redox species with either reversible or irreversible electrode kinetics measured at electrodes modified with porous layers. Most notably a large perturbation of the expected peak current is apparent which can preclude the extraction of meaningful data, for example in respect of surface coverages or in the identification of electro-catalysis. |
| spellingShingle | Ban, Z Kätelhön, F Compton, R Voltammetry of porous layers: Staircase vs analog voltammetry |
| title | Voltammetry of porous layers: Staircase vs analog voltammetry |
| title_full | Voltammetry of porous layers: Staircase vs analog voltammetry |
| title_fullStr | Voltammetry of porous layers: Staircase vs analog voltammetry |
| title_full_unstemmed | Voltammetry of porous layers: Staircase vs analog voltammetry |
| title_short | Voltammetry of porous layers: Staircase vs analog voltammetry |
| title_sort | voltammetry of porous layers staircase vs analog voltammetry |
| work_keys_str_mv | AT banz voltammetryofporouslayersstaircasevsanalogvoltammetry AT katelhonf voltammetryofporouslayersstaircasevsanalogvoltammetry AT comptonr voltammetryofporouslayersstaircasevsanalogvoltammetry |