Radiosynthesis of [18F]ArylSCF2H using aryl boronic acids, S-(chlorofluoromethyl)benzenesulfonothioate and [18F]fluoride

Radiosynthesis of [18F]ArylSCF2H using aryl boronic acids, S-(chlorofluoromethyl)benzenesulfonothioate and [18F]fluoride

Herein, we report a mild and practical protocol for the copper-catalyzed chlorofluoromethylthiolation of (hetero)aryl boronic acids with the novel reagent PhSO2SCFClH. The resulting products are amenable to halogen exchange 18F-fluorination with cyclotron-produced [18F]fluoride affording [18F]ArSCF2...

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Dades bibliogràfiques
Autors principals:	Zhao, Q, Isenegger, PG, Wilson, TC, Sap, JBI, Guibbal, F, Lu, L, Gouverneur, V, Shen, Q
Format:	Journal article
Idioma:	English
Publicat:	Chinese Chemical Society 2020

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