Oxidative radical cyclisations for the synthesis of lactones

The object of study of this thesis lies on the optimisation of the oxidative radical cyclisation methodology for the preferential formation of gamma-lactones from unsaturated alkyl malonate derivatives. Chapter 1 introduces the concept of free...

Disgrifiad llawn

Manylion Llyfryddiaeth
Prif Awdur:	Martinez, S
Awduron Eraill:	Burton, J
Fformat:	Traethawd Ymchwil
Iaith:	English
Cyhoeddwyd:	2017
Pynciau:	Organic Chemistry

Eitemau Tebyg

Oxidative radical cyclisations for total synthesis
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Cyhoeddwyd: (2013)

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Synthesis of (−)-deoxynupharidine by allenic hydroxylamine cyclisation
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Cyclisation reactions for the synthesis of natural and unnatural piperidines
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Synthesis of polyhydroxylated alkaloids via allene cyclisation
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Synthesis of piperidine natural products by allenic cyclisation
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The Aza-Bohlmann cyclisation and the synthesis of Pandanus alkaloids
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Palladium-catalysed cyclisations of bromoenynamides in the synthesis and applications of amidodienes
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Synthesis of γ-lactone and δ-lactone analogues of Atranone F via radical cyclisation approach
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The development and applications of the Lewis acid-mediated osmium-catalysed oxidative cyclisation
gan: Winship, PCM
Cyhoeddwyd: (2011)

Synthesis of curvulone B and allahabadolactone, and the development of a diastereoselective Tsuji-Trost cyclisation
gan: Wang, Kongchen
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Cyclisation cascades via reactive iminium intermediates
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Catalytic reductive cyclisations of amides using Vaska's complex
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Cyhoeddwyd: (2020)

Synthesis of 2,4,6-trisubstituted pyridines via an olefin cross-metathesis/Heck-cyclisation-elimination sequence.
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Palladium-catalysed cascade cyclisation of alkynyl silanes and studies towards rubriflordilactone A
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Stereoselective cyclisation cascades mediated by carbon electrophiles to access novel polycyclic scaffolds
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Synthesis of complex γ-lactones mediated by manganese(III)
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Synthesis of lactone-based conjugated polymers for recently emerging n-type organic thermoelectrics and electrochemical transistors
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Synthesis of block copolymers by mechanistic transformation from reversible complexation mediated living radical polymerization to the photoinduced radical oxidation/addition/deactivation process
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Tuneable radical cyclisations: a tin-free approach towards tricyclic and spirocyclic heterocycles via a common precursor
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Generation and reversible cyclisation of furfurylic radicals
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Radical cascades using enantioenriched 7-azabenzonorbornenes and their applications in synthesis
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Manganese(III)-mediated oxidative free-radical cyclisations of allenyl malonates
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Naturally occurring sesquiterpene lactones and their semi-synthetic derivatives modulate PGE2 levels by decreasing COX2 activity and expression
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Synthesis of nitrogen-substituted pyran-2-ones via radical cyclisation approach
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Synthesis of chiral cyclohexanes and carbasugars by 6-exo-dig radical cyclisation reactions
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Radical-mediated diamination of alkenes with phenylhydrazine and azodicarboxylates : highly diastereoselective synthesis of trans-diamines from cycloalkenes
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Synthesis of polyfluoroalkyl aza-polycyclic aromatic hydrocarbons enabled by addition of perfluoroalkyl radicals onto vinyl azides
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Chiral nitroarenes as enantioselective single-electron-transfer oxidants for carbene-catalyzed radical reactions
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Free radical reactions /
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