Single and double stereoselective fluorination of (E)-allylsilanes
Acyclic allylic monofluorides were prepared by electrophilic fluorination of branched (E)-allylsilanes with Selectfluor. These reactions proceeded with efficient transfer of chirality from the silylated to the fluorinated stereocentre. Upon double fluorination, an unsymmetrical ethyl <em>syn&l...
Автори: | , , , |
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Формат: | Journal article |
Мова: | English |
Опубліковано: |
Beilstein Institut
2007
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Предмети: |
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Single and double stereoselective fluorination of (E)-allylsilanes.
Опубліковано 2007
Journal article