The selective preparation and Suzuki coupling reactivity of cyclic 1,3-dione derived mono- and ditriflates
The combination of triflic anhydride and 2,6-di-tert-butyl-4-methylpyridine was found to be a selective reagent system for the conversion of cyclic 1,3-diones to the corresponding monotriflate derivatives. The use of N-(5-chloro-2-pyridyl)triflimide together with KHMDS was selective for the preparat...
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| Format: | Journal article |
| Language: | English |
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2001
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| _version_ | 1797067281283416064 |
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| author | Willis, M Claverie, C |
| author_facet | Willis, M Claverie, C |
| author_sort | Willis, M |
| collection | OXFORD |
| description | The combination of triflic anhydride and 2,6-di-tert-butyl-4-methylpyridine was found to be a selective reagent system for the conversion of cyclic 1,3-diones to the corresponding monotriflate derivatives. The use of N-(5-chloro-2-pyridyl)triflimide together with KHMDS was selective for the preparation of the corresponding ditriflates. The Suzuki coupling reactivity of both the mono- and ditriflates was also explored. © 2001 Elsevier Science Ltd. |
| first_indexed | 2024-03-06T21:54:04Z |
| format | Journal article |
| id | oxford-uuid:4c4a3d8d-3de3-4bbf-8d8a-ec99d535ddc3 |
| institution | University of Oxford |
| language | English |
| last_indexed | 2024-03-06T21:54:04Z |
| publishDate | 2001 |
| record_format | dspace |
| spelling | oxford-uuid:4c4a3d8d-3de3-4bbf-8d8a-ec99d535ddc32022-03-26T15:48:41ZThe selective preparation and Suzuki coupling reactivity of cyclic 1,3-dione derived mono- and ditriflatesJournal articlehttp://purl.org/coar/resource_type/c_dcae04bcuuid:4c4a3d8d-3de3-4bbf-8d8a-ec99d535ddc3EnglishSymplectic Elements at Oxford2001Willis, MClaverie, CThe combination of triflic anhydride and 2,6-di-tert-butyl-4-methylpyridine was found to be a selective reagent system for the conversion of cyclic 1,3-diones to the corresponding monotriflate derivatives. The use of N-(5-chloro-2-pyridyl)triflimide together with KHMDS was selective for the preparation of the corresponding ditriflates. The Suzuki coupling reactivity of both the mono- and ditriflates was also explored. © 2001 Elsevier Science Ltd. |
| spellingShingle | Willis, M Claverie, C The selective preparation and Suzuki coupling reactivity of cyclic 1,3-dione derived mono- and ditriflates |
| title | The selective preparation and Suzuki coupling reactivity of cyclic 1,3-dione derived mono- and ditriflates |
| title_full | The selective preparation and Suzuki coupling reactivity of cyclic 1,3-dione derived mono- and ditriflates |
| title_fullStr | The selective preparation and Suzuki coupling reactivity of cyclic 1,3-dione derived mono- and ditriflates |
| title_full_unstemmed | The selective preparation and Suzuki coupling reactivity of cyclic 1,3-dione derived mono- and ditriflates |
| title_short | The selective preparation and Suzuki coupling reactivity of cyclic 1,3-dione derived mono- and ditriflates |
| title_sort | selective preparation and suzuki coupling reactivity of cyclic 1 3 dione derived mono and ditriflates |
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