New titanium imido complexes containing piperazine-based diamido-diamine ligands

Syntheses of the new piperazine derivatives 1,4-bis(2-amino-4-tert-butylbenzyl)piperazine (2) and 1,4-bis(2-trimethylsilylamino-4-R-benzyl)piperazine (R=H 3 or But 4; H2L1 and H2L2, respectively) are described along with the X-ray crystal structure of 2. Treatment of H2L1 and H2L2 with n-butyl lithi...

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Main Authors: Lloyd, J, Vatsadze, S, Robson, D, Blake, A, Mountford, P
格式: Journal article
语言:English
出版: 1999