[Pb9CdCdPb9]6-: a Zintl cluster anion with an unsupported cadmium-cadmium bond.

Reaction of an ethylenediamine solution of the intermetallic Zintl phase K4Pb9 with dimesitylcadmium yielded the dimeric Zintl ion [Pb9Cd-CdPb9]6- in low crystalline yield. The cluster anion exhibits a Cd-Cd bond and was structurally characterised by single crystal X-ray diffraction in [K(2,2,2-cryp...

Disgrifiad llawn

Manylion Llyfryddiaeth
Prif Awduron: Zhou, B, Denning, MS, Chapman, T, McGrady, J, Goicoechea, J
Fformat: Journal article
Iaith:English
Cyhoeddwyd: 2009