Long-range magnetic ordering in Ba2COS3: A neutron diffraction study

Neutron powder diffraction has been used to determine the magnetic structure of the quasi-one-dimensional compound Ba2CoS3, which contains linear [001] chains of vertex-sharing CoS4 tetrahedra, spaced apart by Ba2+ cations. At 1.5 K the Co2+ cations in the chains are antiferromagnetically ordered wi...

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Main Authors: Headspith, D, Battle, P, Francesconi, MG
Format: Journal article
Language:English
Published: 2007
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author Headspith, D
Battle, P
Francesconi, MG
author_facet Headspith, D
Battle, P
Francesconi, MG
author_sort Headspith, D
collection OXFORD
description Neutron powder diffraction has been used to determine the magnetic structure of the quasi-one-dimensional compound Ba2CoS3, which contains linear [001] chains of vertex-sharing CoS4 tetrahedra, spaced apart by Ba2+ cations. At 1.5 K the Co2+ cations in the chains are antiferromagnetically ordered with an ordered magnetic moment of 1.97(4) μB per cation aligned along [100]. Each Co2+ cation is ferromagnetically aligned with four cation in neighbouring chains and antiferromagnetically aligned with two others. © 2007 Elsevier Inc. All rights reserved.
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spelling oxford-uuid:4df745c1-c5fd-486d-8fc9-49b9c5e12f4a2022-03-26T15:58:23ZLong-range magnetic ordering in Ba2COS3: A neutron diffraction studyJournal articlehttp://purl.org/coar/resource_type/c_dcae04bcuuid:4df745c1-c5fd-486d-8fc9-49b9c5e12f4aEnglishSymplectic Elements at Oxford2007Headspith, DBattle, PFrancesconi, MGNeutron powder diffraction has been used to determine the magnetic structure of the quasi-one-dimensional compound Ba2CoS3, which contains linear [001] chains of vertex-sharing CoS4 tetrahedra, spaced apart by Ba2+ cations. At 1.5 K the Co2+ cations in the chains are antiferromagnetically ordered with an ordered magnetic moment of 1.97(4) μB per cation aligned along [100]. Each Co2+ cation is ferromagnetically aligned with four cation in neighbouring chains and antiferromagnetically aligned with two others. © 2007 Elsevier Inc. All rights reserved.
spellingShingle Headspith, D
Battle, P
Francesconi, MG
Long-range magnetic ordering in Ba2COS3: A neutron diffraction study
title Long-range magnetic ordering in Ba2COS3: A neutron diffraction study
title_full Long-range magnetic ordering in Ba2COS3: A neutron diffraction study
title_fullStr Long-range magnetic ordering in Ba2COS3: A neutron diffraction study
title_full_unstemmed Long-range magnetic ordering in Ba2COS3: A neutron diffraction study
title_short Long-range magnetic ordering in Ba2COS3: A neutron diffraction study
title_sort long range magnetic ordering in ba2cos3 a neutron diffraction study
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AT battlep longrangemagneticorderinginba2cos3aneutrondiffractionstudy
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