A short and efficient stereoselective synthesis of the polyhydroxylated macrolactone (+)-aspicillin

[structures: see text] A short and efficient synthesis of the polyhydroxylated macrolactone (+)-aspicilin 1 using a stereoselective lithium perchlorate mediated addition of allyltributyltin to the equatorially disposed carboxaldehyde of 3 (derived from (R',R',R,S) butane diacetal protected...

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Autori principali: Dixon, D, Foster, A, Ley, S
Natura: Journal article
Lingua:English
Pubblicazione: 2000