[1-Me-1-closo-SnB11 H-11](-) as a potential weakly coordinating anion: Synthesis of Rh(PPh3)(2)(1-Me-closo-SnB11 H-11) and comparisons with Rh(PR3)(2) (1-H-closo-CB11 H-(11))
The closo-stannaborane salt [Rh(PPh3)2-(nbd)][1-Me-1- closo-SnB11H11] reacts with H2 in CH 2Cl2 solution to afford the contact ion-pair Rh(PPh 3)2(1-Me-closo-SnB11H11), which has been characterized in solution and the solid state by X-ray diffraction. © 2006 Wiley Periodicals, Inc.
| Main Authors: | , , , , |
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| Format: | Journal article |
| Language: | English |
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2006
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| _version_ | 1797067676163506176 |
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| author | Molinos, E Player, T Kociok-Kohn, G Ruggerio, G Weller, A |
| author_facet | Molinos, E Player, T Kociok-Kohn, G Ruggerio, G Weller, A |
| author_sort | Molinos, E |
| collection | OXFORD |
| description | The closo-stannaborane salt [Rh(PPh3)2-(nbd)][1-Me-1- closo-SnB11H11] reacts with H2 in CH 2Cl2 solution to afford the contact ion-pair Rh(PPh 3)2(1-Me-closo-SnB11H11), which has been characterized in solution and the solid state by X-ray diffraction. © 2006 Wiley Periodicals, Inc. |
| first_indexed | 2024-03-06T21:59:47Z |
| format | Journal article |
| id | oxford-uuid:4e2da766-bb04-465a-883e-69e180193c9b |
| institution | University of Oxford |
| language | English |
| last_indexed | 2024-03-06T21:59:47Z |
| publishDate | 2006 |
| record_format | dspace |
| spelling | oxford-uuid:4e2da766-bb04-465a-883e-69e180193c9b2022-03-26T15:59:43Z[1-Me-1-closo-SnB11 H-11](-) as a potential weakly coordinating anion: Synthesis of Rh(PPh3)(2)(1-Me-closo-SnB11 H-11) and comparisons with Rh(PR3)(2) (1-H-closo-CB11 H-(11))Journal articlehttp://purl.org/coar/resource_type/c_dcae04bcuuid:4e2da766-bb04-465a-883e-69e180193c9bEnglishSymplectic Elements at Oxford2006Molinos, EPlayer, TKociok-Kohn, GRuggerio, GWeller, AThe closo-stannaborane salt [Rh(PPh3)2-(nbd)][1-Me-1- closo-SnB11H11] reacts with H2 in CH 2Cl2 solution to afford the contact ion-pair Rh(PPh 3)2(1-Me-closo-SnB11H11), which has been characterized in solution and the solid state by X-ray diffraction. © 2006 Wiley Periodicals, Inc. |
| spellingShingle | Molinos, E Player, T Kociok-Kohn, G Ruggerio, G Weller, A [1-Me-1-closo-SnB11 H-11](-) as a potential weakly coordinating anion: Synthesis of Rh(PPh3)(2)(1-Me-closo-SnB11 H-11) and comparisons with Rh(PR3)(2) (1-H-closo-CB11 H-(11)) |
| title | [1-Me-1-closo-SnB11 H-11](-) as a potential weakly coordinating anion: Synthesis of Rh(PPh3)(2)(1-Me-closo-SnB11 H-11) and comparisons with Rh(PR3)(2) (1-H-closo-CB11 H-(11)) |
| title_full | [1-Me-1-closo-SnB11 H-11](-) as a potential weakly coordinating anion: Synthesis of Rh(PPh3)(2)(1-Me-closo-SnB11 H-11) and comparisons with Rh(PR3)(2) (1-H-closo-CB11 H-(11)) |
| title_fullStr | [1-Me-1-closo-SnB11 H-11](-) as a potential weakly coordinating anion: Synthesis of Rh(PPh3)(2)(1-Me-closo-SnB11 H-11) and comparisons with Rh(PR3)(2) (1-H-closo-CB11 H-(11)) |
| title_full_unstemmed | [1-Me-1-closo-SnB11 H-11](-) as a potential weakly coordinating anion: Synthesis of Rh(PPh3)(2)(1-Me-closo-SnB11 H-11) and comparisons with Rh(PR3)(2) (1-H-closo-CB11 H-(11)) |
| title_short | [1-Me-1-closo-SnB11 H-11](-) as a potential weakly coordinating anion: Synthesis of Rh(PPh3)(2)(1-Me-closo-SnB11 H-11) and comparisons with Rh(PR3)(2) (1-H-closo-CB11 H-(11)) |
| title_sort | 1 me 1 closo snb11 h 11 as a potential weakly coordinating anion synthesis of rh pph3 2 1 me closo snb11 h 11 and comparisons with rh pr3 2 1 h closo cb11 h 11 |
| work_keys_str_mv | AT molinose 1me1clososnb11h11asapotentialweaklycoordinatinganionsynthesisofrhpph321meclososnb11h11andcomparisonswithrhpr321hclosocb11h11 AT playert 1me1clososnb11h11asapotentialweaklycoordinatinganionsynthesisofrhpph321meclososnb11h11andcomparisonswithrhpr321hclosocb11h11 AT kociokkohng 1me1clososnb11h11asapotentialweaklycoordinatinganionsynthesisofrhpph321meclososnb11h11andcomparisonswithrhpr321hclosocb11h11 AT ruggeriog 1me1clososnb11h11asapotentialweaklycoordinatinganionsynthesisofrhpph321meclososnb11h11andcomparisonswithrhpr321hclosocb11h11 AT wellera 1me1clososnb11h11asapotentialweaklycoordinatinganionsynthesisofrhpph321meclososnb11h11andcomparisonswithrhpr321hclosocb11h11 |