New interlocked molecules generated from a podand containing urea units and imidazolium salts using an anion template
A podand containing urea units (L) was found to form interlocked structures with 2,5-dihexylamide imidazolium salts (3·X), 2,5-dihexyl imidazolium salts (4·X), and 2,5-dihexyl benzoimidazolium salts (5·X), where X=Cl-, Br-, and PF6- using anions as templates. The binding ability of L and guest molec...
| Main Authors: | , , , |
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| Format: | Journal article |
| Language: | English |
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2004
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| _version_ | 1797067713530560512 |
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| author | Tomapatanaget, B Tuntulani, T Wisner, J Beer, P |
| author_facet | Tomapatanaget, B Tuntulani, T Wisner, J Beer, P |
| author_sort | Tomapatanaget, B |
| collection | OXFORD |
| description | A podand containing urea units (L) was found to form interlocked structures with 2,5-dihexylamide imidazolium salts (3·X), 2,5-dihexyl imidazolium salts (4·X), and 2,5-dihexyl benzoimidazolium salts (5·X), where X=Cl-, Br-, and PF6- using anions as templates. The binding ability of L and guest molecules was evaluated by 1H NMR titrations in CDCl3. It was found that L could form complexes with guest molecules in the following order, 3·X>5·X>4·X. Stabilities of the complexes also depended on shape of the templated anions: Cl->Br -≫PF6-. Hydrogen bonding and π-π stacking interactions played an important role in the self-assembling of these interlocked molecules. © 2003 Elsevier Ltd. All rights reserved. |
| first_indexed | 2024-03-06T22:00:14Z |
| format | Journal article |
| id | oxford-uuid:4e5460f8-798b-403d-a918-9fd5c428bc56 |
| institution | University of Oxford |
| language | English |
| last_indexed | 2024-03-06T22:00:14Z |
| publishDate | 2004 |
| record_format | dspace |
| spelling | oxford-uuid:4e5460f8-798b-403d-a918-9fd5c428bc562022-03-26T16:00:35ZNew interlocked molecules generated from a podand containing urea units and imidazolium salts using an anion templateJournal articlehttp://purl.org/coar/resource_type/c_dcae04bcuuid:4e5460f8-798b-403d-a918-9fd5c428bc56EnglishSymplectic Elements at Oxford2004Tomapatanaget, BTuntulani, TWisner, JBeer, PA podand containing urea units (L) was found to form interlocked structures with 2,5-dihexylamide imidazolium salts (3·X), 2,5-dihexyl imidazolium salts (4·X), and 2,5-dihexyl benzoimidazolium salts (5·X), where X=Cl-, Br-, and PF6- using anions as templates. The binding ability of L and guest molecules was evaluated by 1H NMR titrations in CDCl3. It was found that L could form complexes with guest molecules in the following order, 3·X>5·X>4·X. Stabilities of the complexes also depended on shape of the templated anions: Cl->Br -≫PF6-. Hydrogen bonding and π-π stacking interactions played an important role in the self-assembling of these interlocked molecules. © 2003 Elsevier Ltd. All rights reserved. |
| spellingShingle | Tomapatanaget, B Tuntulani, T Wisner, J Beer, P New interlocked molecules generated from a podand containing urea units and imidazolium salts using an anion template |
| title | New interlocked molecules generated from a podand containing urea units and imidazolium salts using an anion template |
| title_full | New interlocked molecules generated from a podand containing urea units and imidazolium salts using an anion template |
| title_fullStr | New interlocked molecules generated from a podand containing urea units and imidazolium salts using an anion template |
| title_full_unstemmed | New interlocked molecules generated from a podand containing urea units and imidazolium salts using an anion template |
| title_short | New interlocked molecules generated from a podand containing urea units and imidazolium salts using an anion template |
| title_sort | new interlocked molecules generated from a podand containing urea units and imidazolium salts using an anion template |
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