Ring-opening polymerization of a strained [3]nickelocenophane: a route to polynickelocenes, a class of S = 1 metallopolymers.
We report the synthesis, reactivity studies, and ring-opening polymerization of a tricarba[3]nickelocenophane. The resulting green polynickelocene (5) possesses a -(CH2)3- spacer between the nickelocene units and is shown to be of high molecular weight. SQUID magnetometry measurements indicate that...
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Bibliographic Details
| Main Authors: |
Baljak, S,
Russell, A,
Binding, S,
Haddow, M,
O'Hare, D,
Manners, I |
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| Format: | Journal article
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| Language: | English |
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| Published: |
American Chemical Society
2014
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