Ring-opening polymerization of a strained [3]nickelocenophane: a route to polynickelocenes, a class of S = 1 metallopolymers.
We report the synthesis, reactivity studies, and ring-opening polymerization of a tricarba[3]nickelocenophane. The resulting green polynickelocene (5) possesses a -(CH2)3- spacer between the nickelocene units and is shown to be of high molecular weight. SQUID magnetometry measurements indicate that...
| Main Authors: | , , , , , |
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| Format: | Journal article |
| Language: | English |
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American Chemical Society
2014
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| _version_ | 1797067739019345920 |
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| author | Baljak, S Russell, A Binding, S Haddow, M O'Hare, D Manners, I |
| author_facet | Baljak, S Russell, A Binding, S Haddow, M O'Hare, D Manners, I |
| author_sort | Baljak, S |
| collection | OXFORD |
| description | We report the synthesis, reactivity studies, and ring-opening polymerization of a tricarba[3]nickelocenophane. The resulting green polynickelocene (5) possesses a -(CH2)3- spacer between the nickelocene units and is shown to be of high molecular weight. SQUID magnetometry measurements indicate that 5 is a macromolecular material with an S = 1 repeat unit. |
| first_indexed | 2024-03-06T22:00:37Z |
| format | Journal article |
| id | oxford-uuid:4e7817c9-1efd-4d40-b64a-cf44061ffdf7 |
| institution | University of Oxford |
| language | English |
| last_indexed | 2024-03-06T22:00:37Z |
| publishDate | 2014 |
| publisher | American Chemical Society |
| record_format | dspace |
| spelling | oxford-uuid:4e7817c9-1efd-4d40-b64a-cf44061ffdf72022-03-26T16:01:20ZRing-opening polymerization of a strained [3]nickelocenophane: a route to polynickelocenes, a class of S = 1 metallopolymers.Journal articlehttp://purl.org/coar/resource_type/c_dcae04bcuuid:4e7817c9-1efd-4d40-b64a-cf44061ffdf7EnglishSymplectic Elements at OxfordAmerican Chemical Society2014Baljak, SRussell, ABinding, SHaddow, MO'Hare, DManners, IWe report the synthesis, reactivity studies, and ring-opening polymerization of a tricarba[3]nickelocenophane. The resulting green polynickelocene (5) possesses a -(CH2)3- spacer between the nickelocene units and is shown to be of high molecular weight. SQUID magnetometry measurements indicate that 5 is a macromolecular material with an S = 1 repeat unit. |
| spellingShingle | Baljak, S Russell, A Binding, S Haddow, M O'Hare, D Manners, I Ring-opening polymerization of a strained [3]nickelocenophane: a route to polynickelocenes, a class of S = 1 metallopolymers. |
| title | Ring-opening polymerization of a strained [3]nickelocenophane: a route to polynickelocenes, a class of S = 1 metallopolymers. |
| title_full | Ring-opening polymerization of a strained [3]nickelocenophane: a route to polynickelocenes, a class of S = 1 metallopolymers. |
| title_fullStr | Ring-opening polymerization of a strained [3]nickelocenophane: a route to polynickelocenes, a class of S = 1 metallopolymers. |
| title_full_unstemmed | Ring-opening polymerization of a strained [3]nickelocenophane: a route to polynickelocenes, a class of S = 1 metallopolymers. |
| title_short | Ring-opening polymerization of a strained [3]nickelocenophane: a route to polynickelocenes, a class of S = 1 metallopolymers. |
| title_sort | ring opening polymerization of a strained 3 nickelocenophane a route to polynickelocenes a class of s 1 metallopolymers |
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