Ring-opening polymerization of a strained [3]nickelocenophane: a route to polynickelocenes, a class of S = 1 metallopolymers.

Ring-opening polymerization of a strained [3]nickelocenophane: a route to polynickelocenes, a class of S = 1 metallopolymers.

We report the synthesis, reactivity studies, and ring-opening polymerization of a tricarba[3]nickelocenophane. The resulting green polynickelocene (5) possesses a -(CH2)3- spacer between the nickelocene units and is shown to be of high molecular weight. SQUID magnetometry measurements indicate that...

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Bibliographic Details
Main Authors:	Baljak, S, Russell, A, Binding, S, Haddow, M, O'Hare, D, Manners, I
Format:	Journal article
Language:	English
Published:	American Chemical Society 2014

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