ACTIVITY-COMPOSITION RELATIONSHIPS FOR PYROPE-GROSSULAR GARNET
Activity coefficients (γ) for grossular in pyrope-grossular garnet have been determined experimentally using the divariant assemblage garnet-anorthite-sillimanite (kyanite)-quartz. Values of γ for garnets with 10-12 mole % grossular have been obtained at 1000 °, 1100 °, 1200 ° and 1300 ° C at pressu...
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Format: | Journal article |
Language: | English |
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Springer-Verlag
1975
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_version_ | 1826271916499927040 |
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author | Hensen, B Schmid, R Wood, B |
author_facet | Hensen, B Schmid, R Wood, B |
author_sort | Hensen, B |
collection | OXFORD |
description | Activity coefficients (γ) for grossular in pyrope-grossular garnet have been determined experimentally using the divariant assemblage garnet-anorthite-sillimanite (kyanite)-quartz. Values of γ for garnets with 10-12 mole % grossular have been obtained at 1000 °, 1100 °, 1200 ° and 1300 ° C at pressures between 15 and 21 Kb. The data are consistent with a symmetrical regular solid model for grossular-pyrope solid solutions. The interaction parameter (W) increases linearly with decreasing temperature and is given by W = 7460-4.3 T cals (T in °K). A solvus in the pyrope-grossular solid solution is predicted with a temperature of critical mixing of 629°C±90 ° C. © 1975 Springer-Verlag. |
first_indexed | 2024-03-06T22:04:16Z |
format | Journal article |
id | oxford-uuid:4f9f3bc3-c712-4a30-9647-265b010521e7 |
institution | University of Oxford |
language | English |
last_indexed | 2024-03-06T22:04:16Z |
publishDate | 1975 |
publisher | Springer-Verlag |
record_format | dspace |
spelling | oxford-uuid:4f9f3bc3-c712-4a30-9647-265b010521e72022-03-26T16:08:25ZACTIVITY-COMPOSITION RELATIONSHIPS FOR PYROPE-GROSSULAR GARNETJournal articlehttp://purl.org/coar/resource_type/c_dcae04bcuuid:4f9f3bc3-c712-4a30-9647-265b010521e7EnglishSymplectic Elements at OxfordSpringer-Verlag1975Hensen, BSchmid, RWood, BActivity coefficients (γ) for grossular in pyrope-grossular garnet have been determined experimentally using the divariant assemblage garnet-anorthite-sillimanite (kyanite)-quartz. Values of γ for garnets with 10-12 mole % grossular have been obtained at 1000 °, 1100 °, 1200 ° and 1300 ° C at pressures between 15 and 21 Kb. The data are consistent with a symmetrical regular solid model for grossular-pyrope solid solutions. The interaction parameter (W) increases linearly with decreasing temperature and is given by W = 7460-4.3 T cals (T in °K). A solvus in the pyrope-grossular solid solution is predicted with a temperature of critical mixing of 629°C±90 ° C. © 1975 Springer-Verlag. |
spellingShingle | Hensen, B Schmid, R Wood, B ACTIVITY-COMPOSITION RELATIONSHIPS FOR PYROPE-GROSSULAR GARNET |
title | ACTIVITY-COMPOSITION RELATIONSHIPS FOR PYROPE-GROSSULAR GARNET |
title_full | ACTIVITY-COMPOSITION RELATIONSHIPS FOR PYROPE-GROSSULAR GARNET |
title_fullStr | ACTIVITY-COMPOSITION RELATIONSHIPS FOR PYROPE-GROSSULAR GARNET |
title_full_unstemmed | ACTIVITY-COMPOSITION RELATIONSHIPS FOR PYROPE-GROSSULAR GARNET |
title_short | ACTIVITY-COMPOSITION RELATIONSHIPS FOR PYROPE-GROSSULAR GARNET |
title_sort | activity composition relationships for pyrope grossular garnet |
work_keys_str_mv | AT hensenb activitycompositionrelationshipsforpyropegrossulargarnet AT schmidr activitycompositionrelationshipsforpyropegrossulargarnet AT woodb activitycompositionrelationshipsforpyropegrossulargarnet |