ACTIVITY-COMPOSITION RELATIONSHIPS FOR PYROPE-GROSSULAR GARNET

Activity coefficients (γ) for grossular in pyrope-grossular garnet have been determined experimentally using the divariant assemblage garnet-anorthite-sillimanite (kyanite)-quartz. Values of γ for garnets with 10-12 mole % grossular have been obtained at 1000 °, 1100 °, 1200 ° and 1300 ° C at pressu...

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Main Authors: Hensen, B, Schmid, R, Wood, B
Format: Journal article
Language:English
Published: Springer-Verlag 1975
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author Hensen, B
Schmid, R
Wood, B
author_facet Hensen, B
Schmid, R
Wood, B
author_sort Hensen, B
collection OXFORD
description Activity coefficients (γ) for grossular in pyrope-grossular garnet have been determined experimentally using the divariant assemblage garnet-anorthite-sillimanite (kyanite)-quartz. Values of γ for garnets with 10-12 mole % grossular have been obtained at 1000 °, 1100 °, 1200 ° and 1300 ° C at pressures between 15 and 21 Kb. The data are consistent with a symmetrical regular solid model for grossular-pyrope solid solutions. The interaction parameter (W) increases linearly with decreasing temperature and is given by W = 7460-4.3 T cals (T in °K). A solvus in the pyrope-grossular solid solution is predicted with a temperature of critical mixing of 629°C±90 ° C. © 1975 Springer-Verlag.
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spelling oxford-uuid:4f9f3bc3-c712-4a30-9647-265b010521e72022-03-26T16:08:25ZACTIVITY-COMPOSITION RELATIONSHIPS FOR PYROPE-GROSSULAR GARNETJournal articlehttp://purl.org/coar/resource_type/c_dcae04bcuuid:4f9f3bc3-c712-4a30-9647-265b010521e7EnglishSymplectic Elements at OxfordSpringer-Verlag1975Hensen, BSchmid, RWood, BActivity coefficients (γ) for grossular in pyrope-grossular garnet have been determined experimentally using the divariant assemblage garnet-anorthite-sillimanite (kyanite)-quartz. Values of γ for garnets with 10-12 mole % grossular have been obtained at 1000 °, 1100 °, 1200 ° and 1300 ° C at pressures between 15 and 21 Kb. The data are consistent with a symmetrical regular solid model for grossular-pyrope solid solutions. The interaction parameter (W) increases linearly with decreasing temperature and is given by W = 7460-4.3 T cals (T in °K). A solvus in the pyrope-grossular solid solution is predicted with a temperature of critical mixing of 629°C±90 ° C. © 1975 Springer-Verlag.
spellingShingle Hensen, B
Schmid, R
Wood, B
ACTIVITY-COMPOSITION RELATIONSHIPS FOR PYROPE-GROSSULAR GARNET
title ACTIVITY-COMPOSITION RELATIONSHIPS FOR PYROPE-GROSSULAR GARNET
title_full ACTIVITY-COMPOSITION RELATIONSHIPS FOR PYROPE-GROSSULAR GARNET
title_fullStr ACTIVITY-COMPOSITION RELATIONSHIPS FOR PYROPE-GROSSULAR GARNET
title_full_unstemmed ACTIVITY-COMPOSITION RELATIONSHIPS FOR PYROPE-GROSSULAR GARNET
title_short ACTIVITY-COMPOSITION RELATIONSHIPS FOR PYROPE-GROSSULAR GARNET
title_sort activity composition relationships for pyrope grossular garnet
work_keys_str_mv AT hensenb activitycompositionrelationshipsforpyropegrossulargarnet
AT schmidr activitycompositionrelationshipsforpyropegrossulargarnet
AT woodb activitycompositionrelationshipsforpyropegrossulargarnet