Hybrid biological electron beam and zero-valent nano iron treatment for recalcitrant metalworking fluids
Hybrid approaches for the remediation and detoxification of toxic recalcitrant industrial wastewater were investigated. The focus was waste metalworking fluid, which was selected as a representative model of other waste streams that are toxic, recalcitrant and that require more sustainable routes of...
Main Authors: | , , , , , |
---|---|
Format: | Journal article |
Language: | English |
Published: |
Elsevier
2016
|
_version_ | 1797067997573021696 |
---|---|
author | Thill, P Ager, D Vojnovic, B Tesh, S Scott, T Thompson, I.P, I |
author_facet | Thill, P Ager, D Vojnovic, B Tesh, S Scott, T Thompson, I.P, I |
author_sort | Thill, P |
collection | OXFORD |
description | Hybrid approaches for the remediation and detoxification of toxic recalcitrant industrial wastewater were investigated. The focus was waste metalworking fluid, which was selected as a representative model of other waste streams that are toxic, recalcitrant and that require more sustainable routes of safe disposal. The hybrid approaches included biodegradation, electron beam irradiation and zero-valent nano iron advanced oxidation processes that were employed individually and in sequence employing a factorial design. To compare process performance operationally exhausted and pristine metalworking fluid were compared. Sequential hybrid electron beam irradiation, biological, nanoscale zero-valent iron and biological treatment lead to synergistic detoxification and degradation of both recalcitrant streams, as determined by complementary surrogates and lead to overall improved COD removal of 92.8 ± 1.4% up from 85.9 ± 3.4% for the pristine metalworking fluid. Electron beam pre-treatment enabled more effective biotreatment, achieving 69.5 ± 8% (p = 0.005) and 24.6 ± 4.8% (p = 0.044) COD reductions. |
first_indexed | 2024-03-06T22:04:22Z |
format | Journal article |
id | oxford-uuid:4fa6c191-c19c-45e6-b978-399b6d5731ef |
institution | University of Oxford |
language | English |
last_indexed | 2024-03-06T22:04:22Z |
publishDate | 2016 |
publisher | Elsevier |
record_format | dspace |
spelling | oxford-uuid:4fa6c191-c19c-45e6-b978-399b6d5731ef2022-03-26T16:08:36ZHybrid biological electron beam and zero-valent nano iron treatment for recalcitrant metalworking fluidsJournal articlehttp://purl.org/coar/resource_type/c_dcae04bcuuid:4fa6c191-c19c-45e6-b978-399b6d5731efEnglishSymplectic Elements at OxfordElsevier2016Thill, PAger, DVojnovic, BTesh, SScott, TThompson, I.P, IHybrid approaches for the remediation and detoxification of toxic recalcitrant industrial wastewater were investigated. The focus was waste metalworking fluid, which was selected as a representative model of other waste streams that are toxic, recalcitrant and that require more sustainable routes of safe disposal. The hybrid approaches included biodegradation, electron beam irradiation and zero-valent nano iron advanced oxidation processes that were employed individually and in sequence employing a factorial design. To compare process performance operationally exhausted and pristine metalworking fluid were compared. Sequential hybrid electron beam irradiation, biological, nanoscale zero-valent iron and biological treatment lead to synergistic detoxification and degradation of both recalcitrant streams, as determined by complementary surrogates and lead to overall improved COD removal of 92.8 ± 1.4% up from 85.9 ± 3.4% for the pristine metalworking fluid. Electron beam pre-treatment enabled more effective biotreatment, achieving 69.5 ± 8% (p = 0.005) and 24.6 ± 4.8% (p = 0.044) COD reductions. |
spellingShingle | Thill, P Ager, D Vojnovic, B Tesh, S Scott, T Thompson, I.P, I Hybrid biological electron beam and zero-valent nano iron treatment for recalcitrant metalworking fluids |
title | Hybrid biological electron beam and zero-valent nano iron treatment for recalcitrant metalworking fluids |
title_full | Hybrid biological electron beam and zero-valent nano iron treatment for recalcitrant metalworking fluids |
title_fullStr | Hybrid biological electron beam and zero-valent nano iron treatment for recalcitrant metalworking fluids |
title_full_unstemmed | Hybrid biological electron beam and zero-valent nano iron treatment for recalcitrant metalworking fluids |
title_short | Hybrid biological electron beam and zero-valent nano iron treatment for recalcitrant metalworking fluids |
title_sort | hybrid biological electron beam and zero valent nano iron treatment for recalcitrant metalworking fluids |
work_keys_str_mv | AT thillp hybridbiologicalelectronbeamandzerovalentnanoirontreatmentforrecalcitrantmetalworkingfluids AT agerd hybridbiologicalelectronbeamandzerovalentnanoirontreatmentforrecalcitrantmetalworkingfluids AT vojnovicb hybridbiologicalelectronbeamandzerovalentnanoirontreatmentforrecalcitrantmetalworkingfluids AT teshs hybridbiologicalelectronbeamandzerovalentnanoirontreatmentforrecalcitrantmetalworkingfluids AT scottt hybridbiologicalelectronbeamandzerovalentnanoirontreatmentforrecalcitrantmetalworkingfluids AT thompsonipi hybridbiologicalelectronbeamandzerovalentnanoirontreatmentforrecalcitrantmetalworkingfluids |