An experimental study of the thermodynamic properties of molecularly simple liquid mixtures
<p>The object of this work was to provide accurate experimental values of the primary thermodynamic excess functions — the excess Gibbs energy G<sup>E</sup>, the enthalpy of mixing HE, and the excess volume V<sup>E</sup> — of suitably chosen binary liquid mixtures, with...
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| Format: | Thesis |
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1979
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| _version_ | 1797068009980821504 |
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| author | Lobo, LQ |
| author2 | Staveley, LAK |
| author_facet | Staveley, LAK Lobo, LQ |
| author_sort | Lobo, LQ |
| collection | OXFORD |
| description | <p>The object of this work was to provide accurate experimental values of the primary
thermodynamic excess functions — the excess Gibbs energy G<sup>E</sup>, the enthalpy of mixing HE,
and the excess volume V<sup>E</sup>
— of suitably chosen binary liquid mixtures, with which modern
theories of solutions, especially those which take polarity into account, could be tested.
All the systems studied, therefore, involve at least one (multi-)polar component, this
being selected from the following substances: HCl,N<sub>2</sub>O, C<sub>2</sub>H<sub>4</sub> , CH<sub>4</sub> , CF<sub>4</sub> and C<sub>2</sub>F<sub>6</sub>. Xenon
was used as the second, non-polar component in four of the binary mixtures. G<sup>E</sup> was
derived from vapour pressure measurements, HE determined by calorimetry, and V<sup>E</sup> ob—
tained by a pyknometric technique. The experimental results obtained for each of the
excess properties, M<sup>E</sup>, where generally fitted to a Redlich-Kister-type equation. </p>
<p>[Abstract continued in thesis]</p> |
| first_indexed | 2024-03-06T22:04:33Z |
| format | Thesis |
| id | oxford-uuid:4fb3c936-0ce2-495a-a9af-4e8e2c0ce2e9 |
| institution | University of Oxford |
| last_indexed | 2024-03-06T22:04:33Z |
| publishDate | 1979 |
| record_format | dspace |
| spelling | oxford-uuid:4fb3c936-0ce2-495a-a9af-4e8e2c0ce2e92022-03-26T16:09:07ZAn experimental study of the thermodynamic properties of molecularly simple liquid mixtures Thesishttp://purl.org/coar/resource_type/c_db06uuid:4fb3c936-0ce2-495a-a9af-4e8e2c0ce2e9ORA41979Lobo, LQStaveley, LAK<p>The object of this work was to provide accurate experimental values of the primary thermodynamic excess functions — the excess Gibbs energy G<sup>E</sup>, the enthalpy of mixing HE, and the excess volume V<sup>E</sup> — of suitably chosen binary liquid mixtures, with which modern theories of solutions, especially those which take polarity into account, could be tested. All the systems studied, therefore, involve at least one (multi-)polar component, this being selected from the following substances: HCl,N<sub>2</sub>O, C<sub>2</sub>H<sub>4</sub> , CH<sub>4</sub> , CF<sub>4</sub> and C<sub>2</sub>F<sub>6</sub>. Xenon was used as the second, non-polar component in four of the binary mixtures. G<sup>E</sup> was derived from vapour pressure measurements, HE determined by calorimetry, and V<sup>E</sup> ob— tained by a pyknometric technique. The experimental results obtained for each of the excess properties, M<sup>E</sup>, where generally fitted to a Redlich-Kister-type equation. </p> <p>[Abstract continued in thesis]</p> |
| spellingShingle | Lobo, LQ An experimental study of the thermodynamic properties of molecularly simple liquid mixtures |
| title | An experimental study of the thermodynamic properties of molecularly simple liquid mixtures |
| title_full | An experimental study of the thermodynamic properties of molecularly simple liquid mixtures |
| title_fullStr | An experimental study of the thermodynamic properties of molecularly simple liquid mixtures |
| title_full_unstemmed | An experimental study of the thermodynamic properties of molecularly simple liquid mixtures |
| title_short | An experimental study of the thermodynamic properties of molecularly simple liquid mixtures |
| title_sort | experimental study of the thermodynamic properties of molecularly simple liquid mixtures |
| work_keys_str_mv | AT lobolq anexperimentalstudyofthethermodynamicpropertiesofmolecularlysimpleliquidmixtures AT lobolq experimentalstudyofthethermodynamicpropertiesofmolecularlysimpleliquidmixtures |