Quantitative weaknesses of the Marcus-Hush theory of electrode kinetics revealed by Reverse Scan Square Wave Voltammetry: The reduction of 2-methyl-2-nitropropane at mercury microelectrodes
The Marcus-Hush and Butler-Volmer kinetic electrode models are compared experimentally by studying the reduction of 2-methyl-2-nitropropane in acetonitrile at mercury microelectrodes using Reverse Scan Square Wave Voltammetry. This technique is found to be very sensitive to the electrode kinetics an...
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| Autori principali: |
Laborda, E,
Wang, Y,
Henstridge, M,
Martinez-Ortiz, F,
Molina, A,
Compton, R |
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| Natura: | Journal article
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| Lingua: | English |
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| Pubblicazione: |
2011
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