Ageing-dependent properties of ZnPc/C60 photovoltaic devices

The ZnPc/C60 solar cells with a reasonable energy conversion efficiency of -1.5% were investigated. The samples were aged for 1269 hours upon illumination by the blue LED with peak emission at 475nm. Upon ageing, the devices have shown a strong and fast degradation of the efficiency, short circuit c...

Fuld beskrivelse

Bibliografiske detaljer
Main Authors: Kazukauskas, V, Arlauskas, A, Pranaitis, M, Lessmann, R, Riede, M, Leo, K
Format: Journal article
Sprog:English
Udgivet: 2010
_version_ 1826272052760281088
author Kazukauskas, V
Arlauskas, A
Pranaitis, M
Lessmann, R
Riede, M
Leo, K
author_facet Kazukauskas, V
Arlauskas, A
Pranaitis, M
Lessmann, R
Riede, M
Leo, K
author_sort Kazukauskas, V
collection OXFORD
description The ZnPc/C60 solar cells with a reasonable energy conversion efficiency of -1.5% were investigated. The samples were aged for 1269 hours upon illumination by the blue LED with peak emission at 475nm. Upon ageing, the devices have shown a strong and fast degradation of the efficiency, short circuit current and of the fill factor within several hours followed by a much slower decrease thereof. The carrier mobility dependences on electric field strength at different temperatures were measured by the Charge Extraction by Linearly Increasing Voltage method. The observed drop of device current cannot be explained be only mobility decrease. The increase of the effective barrier height by about 0.1eV from -0.55eV up to -0.65eV was observed in the aged samples. Meanwhile, thermal activation energy values of the electrical conductivity grew from about 0.28eV prior to degradation up to about 0.34eV after ageing. © 2010 - STC "Institute for Scientific Cruystals".
first_indexed 2024-03-06T22:06:27Z
format Journal article
id oxford-uuid:50522736-9600-46bc-b393-46d25c47cd24
institution University of Oxford
language English
last_indexed 2024-03-06T22:06:27Z
publishDate 2010
record_format dspace
spelling oxford-uuid:50522736-9600-46bc-b393-46d25c47cd242022-03-26T16:12:51ZAgeing-dependent properties of ZnPc/C60 photovoltaic devicesJournal articlehttp://purl.org/coar/resource_type/c_dcae04bcuuid:50522736-9600-46bc-b393-46d25c47cd24EnglishSymplectic Elements at Oxford2010Kazukauskas, VArlauskas, APranaitis, MLessmann, RRiede, MLeo, KThe ZnPc/C60 solar cells with a reasonable energy conversion efficiency of -1.5% were investigated. The samples were aged for 1269 hours upon illumination by the blue LED with peak emission at 475nm. Upon ageing, the devices have shown a strong and fast degradation of the efficiency, short circuit current and of the fill factor within several hours followed by a much slower decrease thereof. The carrier mobility dependences on electric field strength at different temperatures were measured by the Charge Extraction by Linearly Increasing Voltage method. The observed drop of device current cannot be explained be only mobility decrease. The increase of the effective barrier height by about 0.1eV from -0.55eV up to -0.65eV was observed in the aged samples. Meanwhile, thermal activation energy values of the electrical conductivity grew from about 0.28eV prior to degradation up to about 0.34eV after ageing. © 2010 - STC "Institute for Scientific Cruystals".
spellingShingle Kazukauskas, V
Arlauskas, A
Pranaitis, M
Lessmann, R
Riede, M
Leo, K
Ageing-dependent properties of ZnPc/C60 photovoltaic devices
title Ageing-dependent properties of ZnPc/C60 photovoltaic devices
title_full Ageing-dependent properties of ZnPc/C60 photovoltaic devices
title_fullStr Ageing-dependent properties of ZnPc/C60 photovoltaic devices
title_full_unstemmed Ageing-dependent properties of ZnPc/C60 photovoltaic devices
title_short Ageing-dependent properties of ZnPc/C60 photovoltaic devices
title_sort ageing dependent properties of znpc c60 photovoltaic devices
work_keys_str_mv AT kazukauskasv ageingdependentpropertiesofznpcc60photovoltaicdevices
AT arlauskasa ageingdependentpropertiesofznpcc60photovoltaicdevices
AT pranaitism ageingdependentpropertiesofznpcc60photovoltaicdevices
AT lessmannr ageingdependentpropertiesofznpcc60photovoltaicdevices
AT riedem ageingdependentpropertiesofznpcc60photovoltaicdevices
AT leok ageingdependentpropertiesofznpcc60photovoltaicdevices