Evidence for concerted ring opening and C-Br bond breaking in UV-excited bromocyclopropane.

Evidence for concerted ring opening and C-Br bond breaking in UV-excited bromocyclopropane.

Photodissociation of gaseous bromocyclopropane via its A-band continuum has been studied at excitation wavelengths ranging from 230 nm to 267 nm. Velocity-map images of ground-state bromine atoms (Br), spin-orbit excited bromine atoms (Br*) and C3H5 hydrocarbon radicals reveal the kinetic energies o...

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Bibliografiske detaljer
Main Authors:	Pandit, S, Preston, T, King, S, Vallance, C, Orr-Ewing, A
Format:	Journal article
Sprog:	English
Udgivet:	American Institute of Physics 2016

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