Rhodium-containing oxide-hydrides: covalently stabilized mixed-anion solids
<p>The first rhodium-containing oxide-hydride phases, LaSrCo<sub>0.5</sub>Rh<sub>0.5</sub>O<sub>3</sub>H and La<sub>0.5</sub>Sr<sub>1.5</sub>Mn<sub>0.5</sub>Rh<sub>0.5</sub>O<sub>3</sub>H, have been...
| Main Authors: | , |
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| Format: | Journal article |
| Language: | English |
| Published: |
Royal Society of Chemistry
2019
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| Summary: | <p>The first rhodium-containing oxide-hydride phases, LaSrCo<sub>0.5</sub>Rh<sub>0.5</sub>O<sub>3</sub>H and La<sub>0.5</sub>Sr<sub>1.5</sub>Mn<sub>0.5</sub>Rh<sub>0.5</sub>O<sub>3</sub>H, have been prepared <em>via</em> topochemical anion exchange. This clearly demonstrates the ability of rhodium, a late 4d transition metal, to kinetically stabilize oxide-hydride lattices, reinforcing the paradigm of covalent stabilization of transition-metal oxide-hydride phases.</p> |
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