Indolyne and aryne distortions and nucleophilic regioselectivites.

Indolyne and aryne distortions and nucleophilic regioselectivites.

Density functional theory computations reproduce the surprisingly high regioselectivities in nucleophilic additions and cycloadditions to 4,5-indolynes and the low regioselectivities in the reactions of 5,6-indolynes. Transition-state distortion energies control the regioselectivities, activating th...

Disgrifiad llawn

Manylion Llyfryddiaeth
Prif Awduron:	Cheong, P, Paton, R, Bronner, S, Im, G, Garg, N, Houk, K
Fformat:	Journal article
Iaith:	English
Cyhoeddwyd:	2010

Eitemau Tebyg

Indolyne experimental and computational studies: synthetic applications and origins of selectivities of nucleophilic additions.
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Synthesis of Oxygenated ortho-Methylbenzaldehydes via Aryne [2+2] Cycloaddition and Benzocyclobutenol Ring Opening
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