Indolyne and aryne distortions and nucleophilic regioselectivites.
Density functional theory computations reproduce the surprisingly high regioselectivities in nucleophilic additions and cycloadditions to 4,5-indolynes and the low regioselectivities in the reactions of 5,6-indolynes. Transition-state distortion energies control the regioselectivities, activating th...
Prif Awduron: | Cheong, P, Paton, R, Bronner, S, Im, G, Garg, N, Houk, K |
---|---|
Fformat: | Journal article |
Iaith: | English |
Cyhoeddwyd: |
2010
|
Eitemau Tebyg
-
Indolyne experimental and computational studies: synthetic applications and origins of selectivities of nucleophilic additions.
gan: Im, G, et al.
Cyhoeddwyd: (2010) -
Indolyne regioselectivities and synthetic applications
gan: Bronner, S, et al.
Cyhoeddwyd: (2011) -
An efficient computational model to predict the synthetic utility of heterocyclic arynes.
gan: Goetz, A, et al.
Cyhoeddwyd: (2012) -
Recent Progress on Multi-Component Reactions Involving Nucleophile, Arynes and CO<sub>2</sub>
gan: Shaoxuan Gong, et al.
Cyhoeddwyd: (2024-07-01) -
Harnessing triaryloxonium ions for aryne generation
gan: Smith, O, et al.
Cyhoeddwyd: (2023)