Doubly carbon-branched pentoses: synthesis of both enantiomers of 2.4-di-C-methyl arabinose and 2-deoxy-2,4-di-C-methyl arabinose using only acetonide protection
An acetonide is the only protecting group used in the synthesis of both the enantiomers of 2,4-di-C-methyl arabinose and 2-deoxy-2,4-di-C-methyl arabinose via the enantiomeric 3-C-methyl-l-erythronolactone [from 2-C-methyl-d-ribono-lactone or d-ribose] and 3-C-methyl-d-erythronolactone [from d-tagat...
| Những tác giả chính: | , , , , , , , |
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| Định dạng: | Journal article |
| Ngôn ngữ: | English |
| Được phát hành: |
2009
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| _version_ | 1826272427214110720 |
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| author | Booth, K Jenkinson, S Best, D Fernandez Nieto, F Estevez, R Wormald, M Weymouth-Wilson, A Fleet, G |
| author_facet | Booth, K Jenkinson, S Best, D Fernandez Nieto, F Estevez, R Wormald, M Weymouth-Wilson, A Fleet, G |
| author_sort | Booth, K |
| collection | OXFORD |
| description | An acetonide is the only protecting group used in the synthesis of both the enantiomers of 2,4-di-C-methyl arabinose and 2-deoxy-2,4-di-C-methyl arabinose via the enantiomeric 3-C-methyl-l-erythronolactone [from 2-C-methyl-d-ribono-lactone or d-ribose] and 3-C-methyl-d-erythronolactone [from d-tagatose or l-ribose]. NMR studies on unprotected C-methyl arabinoses show that methyl branching significantly affects the ratios of pyranose and furanose forms present in aqueous solution. © 2009 Elsevier Ltd. All rights reserved. |
| first_indexed | 2024-03-06T22:12:24Z |
| format | Journal article |
| id | oxford-uuid:52446a12-49b0-41d2-84e7-0dde82ca79b9 |
| institution | University of Oxford |
| language | English |
| last_indexed | 2024-03-06T22:12:24Z |
| publishDate | 2009 |
| record_format | dspace |
| spelling | oxford-uuid:52446a12-49b0-41d2-84e7-0dde82ca79b92022-03-26T16:24:32ZDoubly carbon-branched pentoses: synthesis of both enantiomers of 2.4-di-C-methyl arabinose and 2-deoxy-2,4-di-C-methyl arabinose using only acetonide protectionJournal articlehttp://purl.org/coar/resource_type/c_dcae04bcuuid:52446a12-49b0-41d2-84e7-0dde82ca79b9EnglishSymplectic Elements at Oxford2009Booth, KJenkinson, SBest, DFernandez Nieto, FEstevez, RWormald, MWeymouth-Wilson, AFleet, GAn acetonide is the only protecting group used in the synthesis of both the enantiomers of 2,4-di-C-methyl arabinose and 2-deoxy-2,4-di-C-methyl arabinose via the enantiomeric 3-C-methyl-l-erythronolactone [from 2-C-methyl-d-ribono-lactone or d-ribose] and 3-C-methyl-d-erythronolactone [from d-tagatose or l-ribose]. NMR studies on unprotected C-methyl arabinoses show that methyl branching significantly affects the ratios of pyranose and furanose forms present in aqueous solution. © 2009 Elsevier Ltd. All rights reserved. |
| spellingShingle | Booth, K Jenkinson, S Best, D Fernandez Nieto, F Estevez, R Wormald, M Weymouth-Wilson, A Fleet, G Doubly carbon-branched pentoses: synthesis of both enantiomers of 2.4-di-C-methyl arabinose and 2-deoxy-2,4-di-C-methyl arabinose using only acetonide protection |
| title | Doubly carbon-branched pentoses: synthesis of both enantiomers of 2.4-di-C-methyl arabinose and 2-deoxy-2,4-di-C-methyl arabinose using only acetonide protection |
| title_full | Doubly carbon-branched pentoses: synthesis of both enantiomers of 2.4-di-C-methyl arabinose and 2-deoxy-2,4-di-C-methyl arabinose using only acetonide protection |
| title_fullStr | Doubly carbon-branched pentoses: synthesis of both enantiomers of 2.4-di-C-methyl arabinose and 2-deoxy-2,4-di-C-methyl arabinose using only acetonide protection |
| title_full_unstemmed | Doubly carbon-branched pentoses: synthesis of both enantiomers of 2.4-di-C-methyl arabinose and 2-deoxy-2,4-di-C-methyl arabinose using only acetonide protection |
| title_short | Doubly carbon-branched pentoses: synthesis of both enantiomers of 2.4-di-C-methyl arabinose and 2-deoxy-2,4-di-C-methyl arabinose using only acetonide protection |
| title_sort | doubly carbon branched pentoses synthesis of both enantiomers of 2 4 di c methyl arabinose and 2 deoxy 2 4 di c methyl arabinose using only acetonide protection |
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