Heterogeneous or homogeneous? A case study involving palladium-containing perovskites in the Suzuki reaction

The utility of a series of palladium-containing perovskite catalysts in the Suzuki reaction is described; turnover numbers of up to 400,000 are reported. A detailed investigation into the mode of action of these catalysts encompassing kinetic studies, catalyst poisoning, microscopy and three-phase t...

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Main Authors: Andrews, S, Stepan, A, Tanaka, H, Ley, S, Smith, M
Format: Journal article
Sprog:English
Udgivet: 2005
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author Andrews, S
Stepan, A
Tanaka, H
Ley, S
Smith, M
author_facet Andrews, S
Stepan, A
Tanaka, H
Ley, S
Smith, M
author_sort Andrews, S
collection OXFORD
description The utility of a series of palladium-containing perovskite catalysts in the Suzuki reaction is described; turnover numbers of up to 400,000 are reported. A detailed investigation into the mode of action of these catalysts encompassing kinetic studies, catalyst poisoning, microscopy and three-phase tests demonstrate that these heterogeneous materials are pre-catalysts that operate by a solution-phase mechanism. © 2005 Wiley-VCH Verlag GmbH and Co. KGaA.
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spelling oxford-uuid:526a5ad0-e467-469a-a1e7-c8c16ca047372022-03-26T16:25:25ZHeterogeneous or homogeneous? A case study involving palladium-containing perovskites in the Suzuki reactionJournal articlehttp://purl.org/coar/resource_type/c_dcae04bcuuid:526a5ad0-e467-469a-a1e7-c8c16ca04737EnglishSymplectic Elements at Oxford2005Andrews, SStepan, ATanaka, HLey, SSmith, MThe utility of a series of palladium-containing perovskite catalysts in the Suzuki reaction is described; turnover numbers of up to 400,000 are reported. A detailed investigation into the mode of action of these catalysts encompassing kinetic studies, catalyst poisoning, microscopy and three-phase tests demonstrate that these heterogeneous materials are pre-catalysts that operate by a solution-phase mechanism. © 2005 Wiley-VCH Verlag GmbH and Co. KGaA.
spellingShingle Andrews, S
Stepan, A
Tanaka, H
Ley, S
Smith, M
Heterogeneous or homogeneous? A case study involving palladium-containing perovskites in the Suzuki reaction
title Heterogeneous or homogeneous? A case study involving palladium-containing perovskites in the Suzuki reaction
title_full Heterogeneous or homogeneous? A case study involving palladium-containing perovskites in the Suzuki reaction
title_fullStr Heterogeneous or homogeneous? A case study involving palladium-containing perovskites in the Suzuki reaction
title_full_unstemmed Heterogeneous or homogeneous? A case study involving palladium-containing perovskites in the Suzuki reaction
title_short Heterogeneous or homogeneous? A case study involving palladium-containing perovskites in the Suzuki reaction
title_sort heterogeneous or homogeneous a case study involving palladium containing perovskites in the suzuki reaction
work_keys_str_mv AT andrewss heterogeneousorhomogeneousacasestudyinvolvingpalladiumcontainingperovskitesinthesuzukireaction
AT stepana heterogeneousorhomogeneousacasestudyinvolvingpalladiumcontainingperovskitesinthesuzukireaction
AT tanakah heterogeneousorhomogeneousacasestudyinvolvingpalladiumcontainingperovskitesinthesuzukireaction
AT leys heterogeneousorhomogeneousacasestudyinvolvingpalladiumcontainingperovskitesinthesuzukireaction
AT smithm heterogeneousorhomogeneousacasestudyinvolvingpalladiumcontainingperovskitesinthesuzukireaction