Heterogeneous or homogeneous? A case study involving palladium-containing perovskites in the Suzuki reaction
The utility of a series of palladium-containing perovskite catalysts in the Suzuki reaction is described; turnover numbers of up to 400,000 are reported. A detailed investigation into the mode of action of these catalysts encompassing kinetic studies, catalyst poisoning, microscopy and three-phase t...
Hauptverfasser: | , , , , |
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Format: | Journal article |
Sprache: | English |
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2005
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_version_ | 1826272458520395776 |
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author | Andrews, S Stepan, A Tanaka, H Ley, S Smith, M |
author_facet | Andrews, S Stepan, A Tanaka, H Ley, S Smith, M |
author_sort | Andrews, S |
collection | OXFORD |
description | The utility of a series of palladium-containing perovskite catalysts in the Suzuki reaction is described; turnover numbers of up to 400,000 are reported. A detailed investigation into the mode of action of these catalysts encompassing kinetic studies, catalyst poisoning, microscopy and three-phase tests demonstrate that these heterogeneous materials are pre-catalysts that operate by a solution-phase mechanism. © 2005 Wiley-VCH Verlag GmbH and Co. KGaA. |
first_indexed | 2024-03-06T22:12:54Z |
format | Journal article |
id | oxford-uuid:526a5ad0-e467-469a-a1e7-c8c16ca04737 |
institution | University of Oxford |
language | English |
last_indexed | 2024-03-06T22:12:54Z |
publishDate | 2005 |
record_format | dspace |
spelling | oxford-uuid:526a5ad0-e467-469a-a1e7-c8c16ca047372022-03-26T16:25:25ZHeterogeneous or homogeneous? A case study involving palladium-containing perovskites in the Suzuki reactionJournal articlehttp://purl.org/coar/resource_type/c_dcae04bcuuid:526a5ad0-e467-469a-a1e7-c8c16ca04737EnglishSymplectic Elements at Oxford2005Andrews, SStepan, ATanaka, HLey, SSmith, MThe utility of a series of palladium-containing perovskite catalysts in the Suzuki reaction is described; turnover numbers of up to 400,000 are reported. A detailed investigation into the mode of action of these catalysts encompassing kinetic studies, catalyst poisoning, microscopy and three-phase tests demonstrate that these heterogeneous materials are pre-catalysts that operate by a solution-phase mechanism. © 2005 Wiley-VCH Verlag GmbH and Co. KGaA. |
spellingShingle | Andrews, S Stepan, A Tanaka, H Ley, S Smith, M Heterogeneous or homogeneous? A case study involving palladium-containing perovskites in the Suzuki reaction |
title | Heterogeneous or homogeneous? A case study involving palladium-containing perovskites in the Suzuki reaction |
title_full | Heterogeneous or homogeneous? A case study involving palladium-containing perovskites in the Suzuki reaction |
title_fullStr | Heterogeneous or homogeneous? A case study involving palladium-containing perovskites in the Suzuki reaction |
title_full_unstemmed | Heterogeneous or homogeneous? A case study involving palladium-containing perovskites in the Suzuki reaction |
title_short | Heterogeneous or homogeneous? A case study involving palladium-containing perovskites in the Suzuki reaction |
title_sort | heterogeneous or homogeneous a case study involving palladium containing perovskites in the suzuki reaction |
work_keys_str_mv | AT andrewss heterogeneousorhomogeneousacasestudyinvolvingpalladiumcontainingperovskitesinthesuzukireaction AT stepana heterogeneousorhomogeneousacasestudyinvolvingpalladiumcontainingperovskitesinthesuzukireaction AT tanakah heterogeneousorhomogeneousacasestudyinvolvingpalladiumcontainingperovskitesinthesuzukireaction AT leys heterogeneousorhomogeneousacasestudyinvolvingpalladiumcontainingperovskitesinthesuzukireaction AT smithm heterogeneousorhomogeneousacasestudyinvolvingpalladiumcontainingperovskitesinthesuzukireaction |