Formation of the first aryl zinc-hydroxy cubane, [ArZn(OH)](4) (Ar=2,4,6-(CF3)(3)C6H2)
The compound [ArZn(OH)]4 (Ar = 2,4,6-(CF3)3C6H2), formed by aggregation of the hydrolysis product of ArZnCl, has a cubane-like structure at 120 K; this is the first structurally characterised example of such a zinc(II) derivative with a simple aromatic group on Zn, and with the bridges formed by -OH...
| Main Authors: | , , , |
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| Format: | Journal article |
| Language: | English |
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2009
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| _version_ | 1797068685647544320 |
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| author | Agnew, C Dillon, K Goeta, A Thompson, A |
| author_facet | Agnew, C Dillon, K Goeta, A Thompson, A |
| author_sort | Agnew, C |
| collection | OXFORD |
| description | The compound [ArZn(OH)]4 (Ar = 2,4,6-(CF3)3C6H2), formed by aggregation of the hydrolysis product of ArZnCl, has a cubane-like structure at 120 K; this is the first structurally characterised example of such a zinc(II) derivative with a simple aromatic group on Zn, and with the bridges formed by -OH rather than -OR groups. It crystallises as a hemisolvate in the triclinic system (P over(1, ̄)), with a single molecule in the asymmetric unit, together with one CHCl3 (or CDCl3) molecule per two molecules of the tetramer. © 2009 Elsevier B.V. All rights reserved. |
| first_indexed | 2024-03-06T22:13:44Z |
| format | Journal article |
| id | oxford-uuid:52b32679-4cd5-42e2-923a-4a51154b4f35 |
| institution | University of Oxford |
| language | English |
| last_indexed | 2024-03-06T22:13:44Z |
| publishDate | 2009 |
| record_format | dspace |
| spelling | oxford-uuid:52b32679-4cd5-42e2-923a-4a51154b4f352022-03-26T16:27:01ZFormation of the first aryl zinc-hydroxy cubane, [ArZn(OH)](4) (Ar=2,4,6-(CF3)(3)C6H2)Journal articlehttp://purl.org/coar/resource_type/c_dcae04bcuuid:52b32679-4cd5-42e2-923a-4a51154b4f35EnglishSymplectic Elements at Oxford2009Agnew, CDillon, KGoeta, AThompson, AThe compound [ArZn(OH)]4 (Ar = 2,4,6-(CF3)3C6H2), formed by aggregation of the hydrolysis product of ArZnCl, has a cubane-like structure at 120 K; this is the first structurally characterised example of such a zinc(II) derivative with a simple aromatic group on Zn, and with the bridges formed by -OH rather than -OR groups. It crystallises as a hemisolvate in the triclinic system (P over(1, ̄)), with a single molecule in the asymmetric unit, together with one CHCl3 (or CDCl3) molecule per two molecules of the tetramer. © 2009 Elsevier B.V. All rights reserved. |
| spellingShingle | Agnew, C Dillon, K Goeta, A Thompson, A Formation of the first aryl zinc-hydroxy cubane, [ArZn(OH)](4) (Ar=2,4,6-(CF3)(3)C6H2) |
| title | Formation of the first aryl zinc-hydroxy cubane, [ArZn(OH)](4) (Ar=2,4,6-(CF3)(3)C6H2) |
| title_full | Formation of the first aryl zinc-hydroxy cubane, [ArZn(OH)](4) (Ar=2,4,6-(CF3)(3)C6H2) |
| title_fullStr | Formation of the first aryl zinc-hydroxy cubane, [ArZn(OH)](4) (Ar=2,4,6-(CF3)(3)C6H2) |
| title_full_unstemmed | Formation of the first aryl zinc-hydroxy cubane, [ArZn(OH)](4) (Ar=2,4,6-(CF3)(3)C6H2) |
| title_short | Formation of the first aryl zinc-hydroxy cubane, [ArZn(OH)](4) (Ar=2,4,6-(CF3)(3)C6H2) |
| title_sort | formation of the first aryl zinc hydroxy cubane arzn oh 4 ar 2 4 6 cf3 3 c6h2 |
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