Nickel(II) tetra-aminophthalocyanine modified MWCNTs as potential nanocomposite materials for the development of supercapacitors
The supercapacitive properties of nickel(ii) tetraaminophthalocyanine (NiTAPc)/multi-walled carbon nanotube (MWCNT) nanocomposite films have been interrogated for the first time and found to possess a maximum specific capacitance of 981 ± 57 F g-1 (200 ± 12 mF cm -2), a maximum power density of 700...
| Main Authors: | , , , , , |
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| Format: | Journal article |
| Language: | English |
| Published: |
2010
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| _version_ | 1797068767964954624 |
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| author | Chidembo, A Ozoemena, K Agboola, B Gupta, V Wildgoose, G Compton, R |
| author_facet | Chidembo, A Ozoemena, K Agboola, B Gupta, V Wildgoose, G Compton, R |
| author_sort | Chidembo, A |
| collection | OXFORD |
| description | The supercapacitive properties of nickel(ii) tetraaminophthalocyanine (NiTAPc)/multi-walled carbon nanotube (MWCNT) nanocomposite films have been interrogated for the first time and found to possess a maximum specific capacitance of 981 ± 57 F g-1 (200 ± 12 mF cm -2), a maximum power density of 700 ± 1 Wkg-1, a maximum specific energy of 134 ± 8 Wh kg-1 and excellent stability of over 1500 charge-discharge continuous cycling. Impedimetric study proves that most of the stored energy of the MWCNT-NiTAPc nanocomposite can be accessible at high frequency (720 Hz). When compared to MWCNTs modified with unsubstituted nickel(ii) phthalocyanine (MWCNT-NiPc) or nickel(ii) tetra-tert-butylphthalocyanine (MWCNT-tBuNiPc), MWCNT-NiTAPc exhibited superior supercapacitive behaviour, possibly due to the influence of nitrogen-containing groups on the phthalocyanine rings. © 2010 The Royal Society of Chemistry. |
| first_indexed | 2024-03-06T22:14:51Z |
| format | Journal article |
| id | oxford-uuid:5308e693-e3f7-4cb1-92c7-d6cb9486e15e |
| institution | University of Oxford |
| language | English |
| last_indexed | 2024-03-06T22:14:51Z |
| publishDate | 2010 |
| record_format | dspace |
| spelling | oxford-uuid:5308e693-e3f7-4cb1-92c7-d6cb9486e15e2022-03-26T16:29:12ZNickel(II) tetra-aminophthalocyanine modified MWCNTs as potential nanocomposite materials for the development of supercapacitorsJournal articlehttp://purl.org/coar/resource_type/c_dcae04bcuuid:5308e693-e3f7-4cb1-92c7-d6cb9486e15eEnglishSymplectic Elements at Oxford2010Chidembo, AOzoemena, KAgboola, BGupta, VWildgoose, GCompton, RThe supercapacitive properties of nickel(ii) tetraaminophthalocyanine (NiTAPc)/multi-walled carbon nanotube (MWCNT) nanocomposite films have been interrogated for the first time and found to possess a maximum specific capacitance of 981 ± 57 F g-1 (200 ± 12 mF cm -2), a maximum power density of 700 ± 1 Wkg-1, a maximum specific energy of 134 ± 8 Wh kg-1 and excellent stability of over 1500 charge-discharge continuous cycling. Impedimetric study proves that most of the stored energy of the MWCNT-NiTAPc nanocomposite can be accessible at high frequency (720 Hz). When compared to MWCNTs modified with unsubstituted nickel(ii) phthalocyanine (MWCNT-NiPc) or nickel(ii) tetra-tert-butylphthalocyanine (MWCNT-tBuNiPc), MWCNT-NiTAPc exhibited superior supercapacitive behaviour, possibly due to the influence of nitrogen-containing groups on the phthalocyanine rings. © 2010 The Royal Society of Chemistry. |
| spellingShingle | Chidembo, A Ozoemena, K Agboola, B Gupta, V Wildgoose, G Compton, R Nickel(II) tetra-aminophthalocyanine modified MWCNTs as potential nanocomposite materials for the development of supercapacitors |
| title | Nickel(II) tetra-aminophthalocyanine modified MWCNTs as potential nanocomposite materials for the development of supercapacitors |
| title_full | Nickel(II) tetra-aminophthalocyanine modified MWCNTs as potential nanocomposite materials for the development of supercapacitors |
| title_fullStr | Nickel(II) tetra-aminophthalocyanine modified MWCNTs as potential nanocomposite materials for the development of supercapacitors |
| title_full_unstemmed | Nickel(II) tetra-aminophthalocyanine modified MWCNTs as potential nanocomposite materials for the development of supercapacitors |
| title_short | Nickel(II) tetra-aminophthalocyanine modified MWCNTs as potential nanocomposite materials for the development of supercapacitors |
| title_sort | nickel ii tetra aminophthalocyanine modified mwcnts as potential nanocomposite materials for the development of supercapacitors |
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