The continuum between hexagonal planar and trigonal planar geometries

New heterometallic hydride complexes that involve the addition of {Mg−H} and {Zn−H} bonds to group 10 transition metals (Pd, Pt) are reported. The side-on coordination of a single {Mg−H} to Pd forms a well-defined σ-complex. In contrast, addition of three {Mg−H} or {Zn−H} bonds to Pd or Pt results i...

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Main Authors: Garçon, M, Phanopoulos, A, Sackman, GA, Richardson, C, White, AJP, Cooper, RI, Edwards, AJ, Crimmin, MR
格式: Journal article
语言:English
出版: Wiley 2022