Hole transport materials with low glass transition temperatures and high solubility for application in solid-state dye-sensitized solar cells.

We present the synthesis and device characterization of new hole transport materials (HTMs) for application in solid-state dye-sensitized solar cells (ssDSSCs). In addition to possessing electrical properties well suited for ssDSSCs, these new HTMs have low glass transition temperatures, low melting...

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Main Authors: Leijtens, T, Ding, I, Giovenzana, T, Bloking, J, McGehee, MD, Sellinger, A
Formato: Journal article
Idioma:English
Publicado em: 2012
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author Leijtens, T
Ding, I
Giovenzana, T
Bloking, J
McGehee, MD
Sellinger, A
author_facet Leijtens, T
Ding, I
Giovenzana, T
Bloking, J
McGehee, MD
Sellinger, A
author_sort Leijtens, T
collection OXFORD
description We present the synthesis and device characterization of new hole transport materials (HTMs) for application in solid-state dye-sensitized solar cells (ssDSSCs). In addition to possessing electrical properties well suited for ssDSSCs, these new HTMs have low glass transition temperatures, low melting points, and high solubility, which make them promising candidates for increased pore filling into mesoporous titania films. Using standard device fabrication methods and Z907 as the sensitizing dye, power conversion efficiencies (PCE) of 2.94% in 2-μm-thick cells were achieved, rivaling the PCE obtained by control devices using the state-of-the-art HTM spiro-OMeTAD. In 6-μm-thick cells, the device performance is shown to be higher than that obtained using spiro-OMeTAD, making these new HTMs promising for preparing high-efficiency ssDSSCs.
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spelling oxford-uuid:54410184-a9f0-48e4-b23f-c126fcc9b77e2022-03-26T16:36:40ZHole transport materials with low glass transition temperatures and high solubility for application in solid-state dye-sensitized solar cells.Journal articlehttp://purl.org/coar/resource_type/c_dcae04bcuuid:54410184-a9f0-48e4-b23f-c126fcc9b77eEnglishSymplectic Elements at Oxford2012Leijtens, TDing, IGiovenzana, TBloking, JMcGehee, MDSellinger, AWe present the synthesis and device characterization of new hole transport materials (HTMs) for application in solid-state dye-sensitized solar cells (ssDSSCs). In addition to possessing electrical properties well suited for ssDSSCs, these new HTMs have low glass transition temperatures, low melting points, and high solubility, which make them promising candidates for increased pore filling into mesoporous titania films. Using standard device fabrication methods and Z907 as the sensitizing dye, power conversion efficiencies (PCE) of 2.94% in 2-μm-thick cells were achieved, rivaling the PCE obtained by control devices using the state-of-the-art HTM spiro-OMeTAD. In 6-μm-thick cells, the device performance is shown to be higher than that obtained using spiro-OMeTAD, making these new HTMs promising for preparing high-efficiency ssDSSCs.
spellingShingle Leijtens, T
Ding, I
Giovenzana, T
Bloking, J
McGehee, MD
Sellinger, A
Hole transport materials with low glass transition temperatures and high solubility for application in solid-state dye-sensitized solar cells.
title Hole transport materials with low glass transition temperatures and high solubility for application in solid-state dye-sensitized solar cells.
title_full Hole transport materials with low glass transition temperatures and high solubility for application in solid-state dye-sensitized solar cells.
title_fullStr Hole transport materials with low glass transition temperatures and high solubility for application in solid-state dye-sensitized solar cells.
title_full_unstemmed Hole transport materials with low glass transition temperatures and high solubility for application in solid-state dye-sensitized solar cells.
title_short Hole transport materials with low glass transition temperatures and high solubility for application in solid-state dye-sensitized solar cells.
title_sort hole transport materials with low glass transition temperatures and high solubility for application in solid state dye sensitized solar cells
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AT giovenzanat holetransportmaterialswithlowglasstransitiontemperaturesandhighsolubilityforapplicationinsolidstatedyesensitizedsolarcells
AT blokingj holetransportmaterialswithlowglasstransitiontemperaturesandhighsolubilityforapplicationinsolidstatedyesensitizedsolarcells
AT mcgeheemd holetransportmaterialswithlowglasstransitiontemperaturesandhighsolubilityforapplicationinsolidstatedyesensitizedsolarcells
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