A sandwich complex with axial symmetry for harnessing the anisotropy in a prolate erbium(iii) ion
A mononuclear ErIII sandwich type complex, [Li(DME)3][ErIII(COT”)2], was isolated using 1,4-bis(trimethylsilyl)cyclooctatetraenyl dianion (COT”). Remarkably, this low-symmetry complex exhibits magnet-like behavior of magnetic remanence and coercivity in the hysteresis loops up to 8 K with an energy...
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| Format: | Journal article |
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Royal Society of Chemistry
2013
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| _version_ | 1797069146078314496 |
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| author | le Roy, J Korobkov, I Murugesu, M |
| author_facet | le Roy, J Korobkov, I Murugesu, M |
| author_sort | le Roy, J |
| collection | OXFORD |
| description | A mononuclear ErIII sandwich type complex, [Li(DME)3][ErIII(COT”)2], was isolated using 1,4-bis(trimethylsilyl)cyclooctatetraenyl dianion (COT”). Remarkably, this low-symmetry complex exhibits magnet-like behavior of magnetic remanence and coercivity in the hysteresis loops up to 8 K with an energy barrier (Ueff) of 187(1) K, thus making this molecule a unique single-ion magnet. |
| first_indexed | 2024-03-06T22:20:10Z |
| format | Journal article |
| id | oxford-uuid:54c34001-7a11-4eee-976b-f2c917ec513a |
| institution | University of Oxford |
| last_indexed | 2024-03-06T22:20:10Z |
| publishDate | 2013 |
| publisher | Royal Society of Chemistry |
| record_format | dspace |
| spelling | oxford-uuid:54c34001-7a11-4eee-976b-f2c917ec513a2022-03-26T16:39:53ZA sandwich complex with axial symmetry for harnessing the anisotropy in a prolate erbium(iii) ionJournal articlehttp://purl.org/coar/resource_type/c_dcae04bcuuid:54c34001-7a11-4eee-976b-f2c917ec513aSymplectic Elements at OxfordRoyal Society of Chemistry2013le Roy, JKorobkov, IMurugesu, MA mononuclear ErIII sandwich type complex, [Li(DME)3][ErIII(COT”)2], was isolated using 1,4-bis(trimethylsilyl)cyclooctatetraenyl dianion (COT”). Remarkably, this low-symmetry complex exhibits magnet-like behavior of magnetic remanence and coercivity in the hysteresis loops up to 8 K with an energy barrier (Ueff) of 187(1) K, thus making this molecule a unique single-ion magnet. |
| spellingShingle | le Roy, J Korobkov, I Murugesu, M A sandwich complex with axial symmetry for harnessing the anisotropy in a prolate erbium(iii) ion |
| title | A sandwich complex with axial symmetry for harnessing the anisotropy in a prolate erbium(iii) ion |
| title_full | A sandwich complex with axial symmetry for harnessing the anisotropy in a prolate erbium(iii) ion |
| title_fullStr | A sandwich complex with axial symmetry for harnessing the anisotropy in a prolate erbium(iii) ion |
| title_full_unstemmed | A sandwich complex with axial symmetry for harnessing the anisotropy in a prolate erbium(iii) ion |
| title_short | A sandwich complex with axial symmetry for harnessing the anisotropy in a prolate erbium(iii) ion |
| title_sort | sandwich complex with axial symmetry for harnessing the anisotropy in a prolate erbium iii ion |
| work_keys_str_mv | AT leroyj asandwichcomplexwithaxialsymmetryforharnessingtheanisotropyinaprolateerbiumiiiion AT korobkovi asandwichcomplexwithaxialsymmetryforharnessingtheanisotropyinaprolateerbiumiiiion AT murugesum asandwichcomplexwithaxialsymmetryforharnessingtheanisotropyinaprolateerbiumiiiion AT leroyj sandwichcomplexwithaxialsymmetryforharnessingtheanisotropyinaprolateerbiumiiiion AT korobkovi sandwichcomplexwithaxialsymmetryforharnessingtheanisotropyinaprolateerbiumiiiion AT murugesum sandwichcomplexwithaxialsymmetryforharnessingtheanisotropyinaprolateerbiumiiiion |