Palladium-catalyzed coupling of ammonia and hydroxide with aryl halides: the direct synthesis of primary anilines and phenols.
(Chemical Equation Presented) Back to basics: Ligand design has allowed two longstanding limitations of Pd-catalyzed C-N and C-O coupling reactions to be overcome. The use of specific sterically demanding electron-rich phosphine ligands makes it possible for ammonia and potassium hydroxide to act as...
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| Format: | Journal article |
| Language: | English |
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2007
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